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283673

Sigma-Aldrich

Copper(II) trifluoromethanesulfonate

98%

Sinônimo(s):

Cu(OTf)2, Copper(II) triflate, Cupric trifluoromethanesulfonate, Trifluoromethanesulfonic acid copper(II) salt

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5 G
R$ 1.100,00
25 G
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5 G
R$ 1.100,00
25 G
R$ 1.903,00

About This Item

Fórmula linear:
(CF3SO3)2Cu
Número CAS:
Peso molecular:
361.68
Beilstein:
4028198
Número CE:
Número MDL:
Código UNSPSC:
12161600
ID de substância PubChem:
NACRES:
NA.22

R$ 1.100,00


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Nível de qualidade

Ensaio

98%

adequação da reação

core: copper
reagent type: catalyst

pf

≥300 °C

cadeia de caracteres SMILES

FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

chave InChI

SBTSVTLGWRLWOD-UHFFFAOYSA-L

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Aplicação

Catalyst for:
  • Mannich condensation
  • Annulative amination
  • Friedel-Crafts reaction
  • Henry reaction
  • Hypervalent iodine reagent-mediated preparation of carbazoles
  • Intramolecular oxidative C-N bond formation for the synthesis of carbazoles
Catalyzes the efficient addition of trimethylsilyl cyanide to carbonyl compounds.[1]

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Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Dario Formenti et al.
Chemical reviews, 119(4), 2611-2680 (2018-12-06)
The reduction of nitro compounds to the corresponding amines is one of the most utilized catalytic processes in the fine and bulk chemical industry. The latest development of catalysts with cheap metals like Fe, Co, Ni, and Cu has led
Ahmed M Senan et al.
Journal of agricultural and food chemistry, 65(32), 6912-6918 (2017-07-19)
Utilization of renewable biomass to partly replace the fossil resources in industrial applications has attracted attention due to the limited fossil feedstock with the increased environmental concerns. This work introduced a modified Wacker-type oxidation for transformation of unsaturated fatty acids/esters
Saravanan, P. et al.
Tetrahedron Letters, 39, 3823-3823 (1998)
Biswarup Chakraborty et al.
Chemistry, an Asian journal, 15(6), 852-859 (2020-02-06)
In the urge of designing noble metal-free and sustainable electrocatalysts for oxygen evolution reaction (OER), herein, a mineral Digenite Cu9 S5 has been prepared from a molecular copper(I) precursor, [{(PyHS)2 CuI (PyHS)}2 ](OTf)2 (1), and utilized as an anode material
Nicole W G Smits et al.
Inorganic chemistry, 58(19), 13007-13019 (2019-09-25)
The structure of the copper complex of the 6-((1-butanethiol)oxy)-tris(2-pyridylmethyl)amine ligand (Cu-tmpa-O(CH2)4SH) anchored to a gold surface has been investigated. To enable covalent attachment of the complex to the gold surface, a heteromolecular self-assembled monolayer (SAM) of butanethiol and a thiol-substituted

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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