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Sigma-Aldrich

Tris(diethylamino)phosphine

97%

Sinônimo(s):

Hexaethyltriamidophosphite, Hexaethyltriaminophosphine, Phosphorous acid tris(diethylamide), Tris(N,N-diethylamino)phosphine, Tris(diethylamido)phosphine, Hexaethylphosphorous triamide

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5 G
R$ 489,00
25 G
R$ 1.535,00

R$ 489,00


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5 G
R$ 489,00
25 G
R$ 1.535,00

About This Item

Fórmula linear:
P[N(C2H5)2]3
Número CAS:
Peso molecular:
247.36
Beilstein:
636187
Número CE:
Número MDL:
Código UNSPSC:
12352001
ID de substância PubChem:
NACRES:
NA.22

R$ 489,00


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Nível de qualidade

Ensaio

97%

Formulário

liquid

adequação da reação

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

índice de refração

n20/D 1.475 (lit.)

p.e.

80-90 °C/10 mmHg (lit.)

densidade

0.903 g/mL at 25 °C (lit.)

grupo funcional

phosphine

cadeia de caracteres SMILES

CCN(CC)P(N(CC)CC)N(CC)CC

InChI

1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3

chave InChI

FDIOSTIIZGWENY-UHFFFAOYSA-N

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Aplicação

Tris(diethylamino)phosphine [(Et2N)3P] can be used as a reagent to synthesize:
  • 1,1′-Dialkylisoindigo derivatives by reacting with various 1-alkylisatins via deoxygenation reaction.[1]
  • 1-Aminomethylisatins by treating with isatin and primary and secondary amines.[2]

It can also be used in the deoxygenation of some cyclic α-diketones using fullerene C60.[3]

Pictogramas

FlameExclamation mark

Palavra indicadora

Warning

Frases de perigo

Declarações de precaução

Classificações de perigo

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

138.2 °F - closed cup

Ponto de fulgor (°C)

59 °C - closed cup

Equipamento de proteção individual

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Slide 1 of 1

1 of 1

Novel 1-Aminomethylisatins: Peculiarities of the Synthesis and the Reaction with Tris (diethylamino) phosphine
Bogdanov AV, et al.
Journal of Heterocyclic Chemistry, 51(4), 1027- 1030 (2014)
Khadga J Karki et al.
Scientific reports, 3, 2287-2287 (2013-07-28)
Multiple exciton generation (MEG) is a process in which more than one exciton is generated upon the absorption of a high energy photon, typically higher than two times the band gap, in semiconductor nanocrystals. It can be observed experimentally using
Facile synthesis of 1, 1′-dialkylisoindigos through deoxygenation reaction of isatins and tris (diethylamino) phosphine
Bogdanov AV, et al.
Synthesis, 2010(19), 3268- 3270 (2010)
K Yamana et al.
Nucleic acids symposium series, (21)(21), 31-32 (1989-01-01)
Utilities of deoxyribonucleoside 3'-O-phosphorbisdiethylamidites in the synthesis of oligodeoxyribonucleotides and their analogues are described.
Irina P Romanova et al.
The Journal of organic chemistry, 76(8), 2548-2557 (2011-03-12)
The reactions of such cyclic α-diketones as acenaphthenequinone, aceanthrenequinone, and N-alkylisatins, with hexaethyltriaminophosphine in the presence of the fullerene C(60), lead to the formation of methanofullerene derivatives under mild conditions. This process proceeds via deoxygenation of the dicarbonyl compound by

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Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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