240532

Allyl alcohol

≥99%

• Sinônimo(s): 2-Propen-1-ol
• Fórmula linear: CH₂=CHCH₂OH
• Número CAS: 107-18-6
• Peso molecular: 58.08
• Beilstein: 605307
• Número CE: 203-470-7
• Número MDL: MFCD00002920
• Código UNSPSC: 12352100
• ID de substância PubChem: 57648048
• NACRES: NA.22

Propriedades

• densidade de vapor: 2 (vs air)
• Nível de qualidade: 200
• pressão de vapor: 23.8 mmHg ( 25 °C)
• Ensaio: ≥99%
• forma: liquid
• temperatura de autoignição: 712 °F
• Lim. expl.: 18 %
• índice de refração: n20/D 1.412 (lit.)
• pb: 96-98 °C (lit.)
• pf: −129 °C (lit.)
• solubilidade: alcohol: miscible(lit.); chloroform: miscible(lit.); diethyl ether: miscible(lit.); water: miscible(lit.)
• densidade: 0.854 g/mL at 25 °C (lit.)
• cadeia de caracteres SMILES: OCC=C
• InChI: 1S/C3H6O/c1-2-3-4/h2,4H,1,3H2
• chave InChI: XXROGKLTLUQVRX-UHFFFAOYSA-N

Descrição

Descrição geral

Allyl alcohol is an industrially important olefinic alcohol. It is the raw material for the synthesis of a wide range of allylic derivatives such as allyl diglycol carbonate, allyl glycidyl ether, 1,4-butanediol, poly(styrene-allyl alcohol), etc. These derivatives find application as lens, coupling agents, plasticizers, crosslinking agents and coating additives. Allyl alcohol can be prepared by the rhenium catalyzed-deoxydehydration of glycerol.

The partial oxidation of allyl alcohol over oxygen-precovered gold surface was studied.

Aplicação

Allyl alcohol may be used in the preparation of propylene via photocatalytic transfer hydrogenolysis in the presence of Pd/TiO₂ catalysts.

Allyl alcohol was used to grow fitter yeast (Saccharomyces cerevisiae).

Used to induce a mouse model of liver damage that has been used to study the mechanisms of hepatotoxicity and hepatic stem cell-mediated repair.

Informações de segurança

• Pictogramas: GHS02,GHS06,GHS08,GHS09
• Palavra indicadora: Danger
• Frases de perigo: H225,H301 + H331,H310,H315,H319,H335,H361fd,H410
• Declarações de precaução: P210 - P273 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• Classificações de perigo: Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 3 - Flammable liquids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 71.6 °F - closed cup
• Ponto de fulgor (°C): 22 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter