159719
Phenylmethanesulfonyl chloride
98%
Sinônimo(s):
α-Toluenesulfonyl chloride
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About This Item
Fórmula linear:
C6H5CH2SO2Cl
Número CAS:
Peso molecular:
190.65
Beilstein:
972806
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
Produtos recomendados
Ensaio
98%
Formulário
solid
pf
92-94 °C (lit.)
grupo funcional
phenyl
cadeia de caracteres SMILES
ClS(=O)(=O)Cc1ccccc1
InChI
1S/C7H7ClO2S/c8-11(9,10)6-7-4-2-1-3-5-7/h1-5H,6H2
chave InChI
OAHKWDDSKCRNFE-UHFFFAOYSA-N
Descrição geral
Phenylmethanesulfonyl chloride is an aliphatic sulfonyl chloride. It reacts with triethylamine in methylene chloride or ether to yield trans-stilbene and cis diphenylethylene sulfone.[1] Its reaction with 1,1-bis(diethylamino)ethane has been studied.[2] Addition of phenylmethanesulfonyl chloride to 1,3-diphenyl-2-pyrrolidinopropene in the presence of water was studied.[3]
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Skin Corr. 1B
Código de classe de armazenamento
8A - Combustible corrosive hazardous materials
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
Equipamento de proteção individual
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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The reaction of 1,1-bs(diethylamino)ethene with phenylmethanesulfonyl chloride.
W E Truce et al.
The Journal of organic chemistry, 30(1), 71-74 (1965-01-01)
Addition of Aliphatic Sulfonyl Chlorides to Enamines. Formation of Acyclic Products.
Looker JJ.
The Journal of Organic Chemistry, 31(9), 2973-2976 (1966)
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