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Sigma-Aldrich

9,10-Dihydroanthracene

97%

Sinônimo(s):

Dihydroanthracene

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About This Item

Fórmula empírica (Notação de Hill):
C14H12
Número CAS:
613-31-0
Peso molecular:
180.25
Beilstein:
1364575
Número CE:
210-336-1
Número MDL:
MFCD00001239
Código UNSPSC:
12352100
ID de substância PubChem:
24847705
NACRES:
NA.22

R$ 453,00

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Ensaio

97%

Formulário

solid

p.e.

312 °C (lit.)

pf

103-107 °C (lit.)

densidade

0.88 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

C1c2ccccc2Cc3ccccc13

InChI

1S/C14H12/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-8H,9-10H2

chave InChI

WPDAVTSOEQEGMS-UHFFFAOYSA-N

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Descrição geral

9,10-Dihydroanthracene causes the transfer hydrogenation of C60 and C70 in the presence of [7H]benzanthrene catalyst[1]. It was oxidatively aromatized to the corresponding anthracene in the presence of molecular oxygen as an oxidant and activated carbon as a promoter in xylene[2].

Aplicação

9,10-Dihydroanthracene(DHA) has been used in a study to assess the hydrogen abstraction capability of valence-delocalized iron complex with DHA in MeCN[3].

Pictogramas

Environment
GHS09

Palavra indicadora

Warning

Frases de perigo

H400

Declarações de precaução

P273

Classificações de perigo

Aquatic Acute 1

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)

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Certificados de análise (COA)

Lot/Batch Number
MKCX0325
MKCW5051
MKCN2161
MKCK2552
MKBW7325V

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Anthracene analytical standard

Supelco

31581

Anthracene

Succinic anhydride ≥99% (GC)

Sigma-Aldrich

239690

Succinic anhydride

9,10-Dimethylanthracene 99%

Sigma-Aldrich

D146706

9,10-Dimethylanthracene

Anthracene for synthesis

Sigma-Aldrich

8.20109

Anthracene

1,4-Cyclohexadiene 97%

Sigma-Aldrich

125415

1,4-Cyclohexadiene

Natsuki Nakamichi et al.
The Journal of organic chemistry, 68(21), 8272-8273 (2003-10-11)
Substituted 9,10-dihydroanthracenes were oxidatively aromatized to the corresponding anthracenes effectively by using molecular oxygen as an oxidant and activated carbon (Darco KB, Aldrich, Inc.) as a promoter in xylene.
[7H] Benzanthrone, a catalyst for the transfer hydrogenation of C60 and C70 by 9, 10-dihydroanthracene.
Gerst M, et al.
Tetrahedron Letters, 34(48), 7729-7732 (1993)
Pengfei Sun et al.
Small (Weinheim an der Bergstrasse, Germany), 16(3), e1906462-e1906462 (2019-12-24)
Lithium primary batteries are still widely used in military, aerospace, medical, and civilian applications despite the omnipresence of rechargeable Li-ion batteries. However, these current primary chemistries are exclusively based on inorganic materials with high cost, low energy density or severe
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Journal of inorganic biochemistry, 197, 110674-110674 (2019-05-21)
Developing coordination complexes of earth abundant metals that can perform substrate oxidations under benign conditions is an ongoing challenge. Herein, the reactivity of two mononuclear Cu-complexes toward the oxidant H2O2 is reported. Both complexes displayed ligand oxidation upon reaction with
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Proceedings of the National Academy of Sciences of the United States of America, 104(52), 20713-20718 (2007-12-21)
Intermediate Q, the methane-oxidizing species of soluble methane monooxygenase, is proposed to have an [Fe(IV)(2)(mu-O)(2)] diamond core. In an effort to obtain a synthetic precedent for such a core, bulk electrolysis at 900 mV (versus Fc(+/0)) has been performed in
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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