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A88255

p-Anisidin

99%

Synonym(e):

4-Amino-anisol, 4-Methoxy-anilin

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Über diesen Artikel

Lineare Formel:
CH3OC6H4NH2
CAS-Nummer:
Molekulargewicht:
123.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
471556
Assay:
99%
Form:
solid
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Quality Segment

assay

99%

form

solid

autoignition temp.

959 °F

bp

240-243 °C (lit.)

mp

56-59 °C (lit.)

SMILES string

COc1ccc(N)cc1

InChI

1S/C7H9NO/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3

InChI key

BHAAPTBBJKJZER-UHFFFAOYSA-N

Application

p-Anisidine can undergo aerobic oxidation in the presence of gold catalysts to form aromatic azo compounds.
p-Anisidine can be used:
  • In the diastereoselective and enantioselective synthesis of CF3-substituted azoridines catalyzed by a chiral Bronsted acid.
  • To prepare 4-organoselenium-quinolines through multi-component Povarov reaction with ethyl glyoxylate and ethynyl(phenyl)selane, catalyzed by Yb(OTf)3.
  • As a starting material to synthesize 3-fluoro-6-methoxyquinoline in two steps.,
  • To prepare N-PMP protected α-aminopropargylphosphonates by reacting with terminal alkynes and diethyl formylphosphonate hydrate using silver(I) triflate as a catalyst.


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Dieser Artikel
A88204A88182334871
description

99%

description

97%

description

≥99%

description

98%

assay

99%

assay

97%

assay

≥99%

assay

98%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

form

solid

form

liquid

form

liquid

form

-

mp

56-59 °C (lit.)

mp

−1-1 °C (lit.)

mp

3-6 °C (lit.)

mp

81-83 °C (lit.)

bp

240-243 °C (lit.)

bp

251 °C (lit.)

bp

225 °C (lit.)

bp

135 °C/18 mmHg (lit.)

autoignition temp.

959 °F

autoignition temp.

-

autoignition temp.

-

autoignition temp.

-


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Signalwort

Danger

Lagerklasse

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Flammpunkt (°F)

251.6 °F - closed cup

Flammpunkt (°C)

122 °C - closed cup

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Carc. 1B - STOT RE 2


Zulassungslistungen

Zulassungslistungen werden hauptsächlich für chemische Produkte erstellt. Für nicht-chemische Produkte können hier nur begrenzte Angaben gemacht werden. Kein Eintrag bedeutet, dass keine der Komponenten gelistet ist. Es liegt in der Verantwortung des Benutzers, die sichere und legale Verwendung des Produkts zu gewährleisten.

90-04-0

CAS No.

90-04-0

CAS No.


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Analysenzertifikate (COA)

Lot/Batch Number

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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