185310

4-Nitroanilin

≥99%

• Synonym(e): 1-Amino-4-nitrobenzene, 4-Amino-1-nitrobenzene, 4-Nitro-1-aminobenzene, 4-Nitrobenzenamine, p-Aminonitrobenze
• Lineare Formel: O₂NC₆H₄NH₂
• CAS-Nummer: 100-01-6
• Molekulargewicht: 138.12
• Beilstein: 508690
• EG-Nummer: 202-810-1
• MDL-Nummer: MFCD00007858
• UNSPSC-Code: 12352100
• eCl@ss: 39032009
• PubChem Substanz-ID: 24850683
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: ≥99%
• Form: powder or crystals
• bp: 260 °C/100 mmHg (lit.)
• mp (Schmelzpunkt): 146-149 °C (lit.)
• Löslichkeit: ethanol: soluble 25 mg/mL, slightly hazy, yellow to brownish-yellow; water: slightly soluble
• Funktionelle Gruppe: nitro
• SMILES String: Nc1ccc(cc1)[N+]([O-])=O
• InChI: 1S/C6H6N2O2/c7-5-1-3-6(4-2-5)8(9)10/h1-4H,7H2
• InChIKey: TYMLOMAKGOJONV-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

4-Nitroaniline forms molecular adducts with 4-amino benzoic acid. It reacts with nitrite ion in hydrochloric acid medium to form 4-nitrophenyldiazonium chloride, which couples with naphth-1-ol in alkaline medium to give a purple azo dye. Photocatalytic degradation of 4-nitroaniline in the presence of TiO₂ suspensions in a batch and continuous annular reactor has been studied.

Anwendung

Produkt chromogener Reaktionen

4-Nitroaniline can be used to prepare:

• p

• -Phenylenediamine using various catalytic systems.
• Poly(4-nitroaniline) thin films for optoelectronic applications.
• An adduct with picric acid.
• A crystalline N-(4-nitrophenyl)-β-alanine by reacting with acrylic acid.

Sicherheitshinweise

• Piktogramme: GHS06,GHS08
• Signalwort: Danger
• H-Sätze: H301 + H311 + H331,H373,H412
• P-Sätze: P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P314
• Gefahreneinstufungen: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - STOT RE 2
• Lagerklassenschlüssel: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): 415.4 °F - closed cup
• Flammpunkt (°C): 213.0 °C - closed cup
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges