930121

RuCl(p-cymene)[(S,S)-Ts-DPEN]

• Synonym(e): [N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzolsulfonamidato-κN]-chloro-[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)-benzol]-ruthenium
• Empirische Formel (Hill-System): C₃₁H₃₅ClN₂O₂RuS
• CAS-Nummer: 192139-90-5
• Molekulargewicht: 636.21
• MDL-Nummer: MFCD14155881
• UNSPSC-Code: 12352116
• NACRES: NA.21

Eigenschaften

• Form: powder or crystals
• Qualitätsniveau: 100
• Grünere Alternativprodukt-Eigenschaften: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp (Schmelzpunkt): >175 °C
• Grünere Alternativprodukt-Kategorie: Aligned
• Lagertemp.: 2-8°C
• SMILES String: CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
• InChI: 1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
• InChIKey: AZFNGPAYDKGCRB-XCPIVNJJSA-M

Beschreibung

Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Anwendung

Catalyst involved in:

• Asymmetric transfer hydrogenation of imines and ketones
• Intramolecular asymmetric reductive amination
• Tandem hydroformylation / hydrogenation of terminal olefins

Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium used for asymmetric hydrogenation reactions.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable