Fortfahren mit
708682
RuCl[(R,R)-TsDPEN](Mesitylen)
90%
Aktionsangebot verfügbar
Synonym(e):
[N-[(1R,2R)-2-(Amino-κN)-1,2- diphenylethyl]-4-methylbenzolsulfonamidato-κN]chloro [(1,2,3,4,5,6-η)-1,3,5-trimethylbenzol]-ruthenium
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| Größe/SKU | Verfügbarkeit | Preis |
|---|---|---|
500 mg | Warenkorb auf Verfügbarkeit prüfen | € 122,00 |
Über diesen Artikel
Quality Segment
assay
90%
form
solid
reaction suitability
reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation
mp
241-249 °C
functional group
amine, phenyl
storage temp.
2-8°C
SMILES string
Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
InChI
1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
InChI key
XBNBOGZUDCYNOJ-AGEKDOICSA-M
Application
- (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
- Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.
Legal Information
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Dieser Artikel | |||
|---|---|---|---|
| description 90% | description 95% | description 90% | description 95% |
| assay 90% | assay 95% | assay 90% | assay 95% |
| reaction suitability reagent type: catalyst | reaction suitability reagent type: catalyst | reaction suitability reagent type: catalyst | reaction suitability core: ruthenium, reagent type: catalyst |
| form solid | form solid | form powder | form crystals |
| functional group phenyl, amine | functional group - | functional group phenyl, amine, fluoro | functional group - |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C |
 90%](/deepweb/assets/sigmaaldrich/product/structures/688/786/21c1946c-cdc5-40d4-bce5-5b82b1239504/640/21c1946c-cdc5-40d4-bce5-5b82b1239504.png)
 95%](/deepweb/assets/sigmaaldrich/product/structures/151/609/eeb99dc1-9ef2-49d8-b255-6b5e2519fee1/640/eeb99dc1-9ef2-49d8-b255-6b5e2519fee1.png)
 90%](/deepweb/assets/sigmaaldrich/product/structures/423/199/db3d73e8-0552-4abe-bdc3-3f9877bea3e6/640/db3d73e8-0552-4abe-bdc3-3f9877bea3e6.png)
![Di-μ-chloro-dichloro-bis-[(1,2,3,4,5,6-η)-1,3,5-trimethylbenzol]-diruthenium 95%](/deepweb/assets/sigmaaldrich/product/structures/488/941/5acf0034-14a0-4448-a9e7-b4112e237d87/640/5acf0034-14a0-4448-a9e7-b4112e237d87.png)
Lagerklasse
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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