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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
Wichtige Dokumente
676578
Bis(tri-tert-butylphosphin)palladium(0)
Synonym(e):
Pd(t-Bu3P)2
About This Item
Empfohlene Produkte
Form
solid
Qualitätsniveau
Eignung der Reaktion
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Grünere Alternativprodukt-Eigenschaften
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp (Schmelzpunkt)
258-272 °C
Grünere Alternativprodukt-Kategorie
, Aligned
Lagertemp.
−20°C
SMILES String
[Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChI
1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;
InChIKey
MXQOYLRVSVOCQT-UHFFFAOYSA-N
Allgemeine Beschreibung
Anwendung
- Katalysator für die Suzuki-Kupplung auf einem mehrfach substituierten sp3-Kohlenstoff[1] (Äq. 1)
- Katalysator für die Stille-Kupplung von Arylchloriden[2] (Äq. 2)
- Katalysator für die Negishi-Kupplung[3] (Äq. 3)
- Katalysator für die Heck-Kupplung zur Bildung tetrasubstituierter Olefine[4] (Äq. 4)
- Katalysator für die Buchwald-Hartwig-Aminierung von Arylhalogeniden[5] (Äq. 5)
- Katalysator für die Carbonylierung von Arylhalogeniden mit Carbamoylsilanen[6] (Äq. 6)
Auf dem Weg zu umweltfreundlicheren Übergangsmetall-katalysierten Prozessen, die durch E-Faktoren quantifiziert werden
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
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Artikel
A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
Protokolle
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
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How is shipping temperature determined? And how is it related to the product storage temperature?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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