673064

Dichloro-bis-(2-methylallyl)-dipalladium

• Synonym(e): Chloro-(2-methylallyl)-palladium(II) Dimer
• Lineare Formel: [CH₂=C(CH₃)CH₂PdCl]₂
• CAS-Nummer: 12081-18-4
• Molekulargewicht: 393.94
• MDL-Nummer: MFCD08561141
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24885140
• NACRES: NA.22

Eigenschaften

• Form: solid
• Eignung der Reaktion: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp (Schmelzpunkt): 168.2-174.0 °C
• Lagertemp.: 2-8°C
• SMILES String: Cl[Pd].Cl[Pd].[CH2][C]([CH2])C.[CH2][C]([CH2])C
• InChI: 1S/2C4H7.2ClH.2Pd/c2*1-4(2)3;;;;/h2*1-2H2,3H3;2*1H;;/q;;;;2*+1/p-2
• InChIKey: XVIHZVZZPKOMRE-UHFFFAOYSA-L

Beschreibung

Anwendung

Catalyst for:

• Asymmetric allylic alkylation reactions
• Suzuki-Miyaura reactions
• Reductive cleavage reactions
• Reaction of alkenyloxiranes with carbon monoxide

Hinweis zur Analyse

Precursor to a Pd(I) catalyst used in cross-coupling of organosilanols.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves