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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
Wichtige Dokumente
222380
Allylpalladium(II)-Chloriddimer
98%
Synonym(e):
Bis((η3-allyl)(chloro)palladium), Di-ο-allyldi-μ-chlorodipalladium, [PdCl(C3H5)]2
About This Item
Empfohlene Produkte
Qualitätsniveau
Assay
98%
Form
solid
Eignung der Reaktion
core: palladium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation
Grünere Alternativprodukt-Eigenschaften
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
Grünere Alternativprodukt-Kategorie
, Aligned
Lagertemp.
2-8°C
SMILES String
Cl[Pd]CC=C.Cl[Pd]CC=C
InChI
1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
InChIKey
TWKVUTXHANJYGH-UHFFFAOYSA-L
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Allgemeine Beschreibung
Anwendung
- Synthese von kationischen Palladiumkatalysatoren, die in der mikrowellengestützten Heck-Arylierung eingesetzt werden.[2]
- Synthese von N-heterozyklischen Carbenpalladium-η3-allylchlorid-Komplexen, die effiziente Katalysatoren für die Suzuki-Miyaura-Kreuzkupplung von Arylbromiden und aktivierten Arylchloriden sind.[3]
- Synthese von 1,4-Diallyl-1,2-dihydroisochinolinen.[4]
- Als Katalysator für eine grünere Buchwald-Hartwig-Kupplung in TPGS-750-M.
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
Signalwort
Warning
H-Sätze
Gefahreneinstufungen
Skin Irrit. 2
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Persönliche Schutzausrüstung
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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Artikel
A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
Protokolle
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
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How is shipping temperature determined? And how is it related to the product storage temperature?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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