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Alle Fotos(2)
Wichtige Dokumente
668729
Diethylzink
packaged for use in deposition systems
Synonym(e):
DEZ, Zinkdiethyl
Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise
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About This Item
Lineare Formel:
(C2H5)2Zn
CAS-Nummer:
Molekulargewicht:
123.51
Beilstein:
3587207
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23
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Form
liquid
Brechungsindex
n20/D 1.498 (lit.)
bp
117 °C (lit.)
mp (Schmelzpunkt)
−28 °C (lit.)
Dichte
1.205 g/mL at 25 °C (lit.)
SMILES String
CC[Zn]CC
InChI
1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;
InChIKey
HQWPLXHWEZZGKY-UHFFFAOYSA-N
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Allgemeine Beschreibung
Atomic number of base material: 30 Zinc
Anwendung
Reacted with water in a low temperature (<200°C) atomic layer deposition of polycrystalline ZnO layers displaying exciton photoluminescence at room temperature.[1]
Signalwort
Danger
H-Sätze
Gefahreneinstufungen
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1
Zusätzliche Gefahrenhinweise
Lagerklassenschlüssel
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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The Journal of organic chemistry, 72(4), 1373-1378 (2007-02-10)
A novel class of sulfinamido alcohol ligands 1-6 was synthesized from (S)-tert-butanesulfinamide. These ligands showed excellent catalytic activities and enantiomeric selectivities in asymmetric additions of diethylzinc to aromatic aldehydes.
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The use of catalytic t-Bu-P4 base dramatically improved the performance of halogen-zinc exchange of aryl iodides, and the arylzinc derivatives were functionalized under copper-free reaction conditions.
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There is a great demand for development of catalyst systems that are not only efficient and highly enantioselective but are also environmentally benign. Herein we report investigations into the catalytic asymmetric addition of alkyl and functionalized alkyl groups to ketones
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