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256781

Sigma-Aldrich

Diethylzink

≥52 wt. % Zn basis

Synonym(e):

DEZ, Zinkdiethyl

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100 G
€ 177,00

€ 177,00


Voraussichtliches Versanddatum28. März 2025


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100 G
€ 177,00

About This Item

Lineare Formel:
(C2H5)2Zn
CAS-Nummer:
Molekulargewicht:
123.51
Beilstein:
3587207
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.22

€ 177,00


Voraussichtliches Versanddatum28. März 2025


Bulk-Bestellung anfordern

Qualitätsniveau

Form

liquid

Konzentration

≥52 wt. % Zn

Brechungsindex

n20/D 1.498 (lit.)

bp

117 °C (lit.)

mp (Schmelzpunkt)

−28 °C (lit.)

Dichte

1.205 g/mL at 25 °C (lit.)

SMILES String

CC[Zn]CC

InChI

1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;

InChIKey

HQWPLXHWEZZGKY-UHFFFAOYSA-N

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Anwendung

Diethylzinc has been used as a zinc precursor for the synthesis of colloidal Cu/Zn-based nanoparticles,[1][2] and zinc on silica catalysts via atomic layer deposition (ALD) technique.[3]

Verpackung

Packaged in Sure/Pac carbon steel cylinders with 1/4" NPTM chrome-plated bronze ball valve

Rechtliche Hinweise

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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Signalwort

Danger

Gefahreneinstufungen

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Kunden haben sich ebenfalls angesehen

Bifunctional hybrid catalysts derived from Cu/Zn-based nanoparticles for single-step dimethyl ether synthesis
Gentzen, M and Habicht, W and Doronkin, DE and Grunwaldt, J-D and Sauer, J and Behrens, S
Catalysis Science & Technology, 6(4), 1054-1063 (2016)
Single-site zinc on silica catalysts for propylene hydrogenation and propane dehydrogenation: Synthesis and reactivity evaluation using an integrated atomic layer deposition-catalysis instrument
Camacho-Bunquin J, et al.
J. Catal., 345, 170-182 (2017)
Bifunctional catalysts based on colloidal Cu/Zn nanoparticles for the direct conversion of synthesis gas to dimethyl ether and hydrocarbons
Gentzen, M and Doronkin, DE and Sheppard, TL and Grunwaldt, J-D and Sauer, J and Behrens, S
Applied Catalysis A: General, 557, 99-107 (2018)
G Lemonnier et al.
The Journal of organic chemistry, 74(11), 4124-4131 (2009-05-06)
A efficient methodology allowing the one-pot stereoselective synthesis of alpha-fluoroacrylates, based on the addition of ethyl dibromofluoroacetate to a carbonyl derivative using diethylzinc as organometallic mediator, is described. Two different pathways have been identified depending on the involved carbonyl partner.
Tummanapalli Satyanarayana et al.
Organic letters, 9(2), 251-253 (2007-01-16)
A strong asymmetric amplification is observed in the addition of diethylzinc on aromatic aldehydes in the presence of the bistriflamide of trans-1,2-diaminocyclohexane 3a. The asymmetric amplification originates from the insolubility of the catalyst precursor 3a of low enantiomeric excess (ee)

Questions

1–4 of 4 Questions  
  1. What is Product 256781, Diethylzinc, soluble in?

    1 answer
    1. The chemicals encyclopedia published by the Royal Society of Chemistry (13th ed.) indicates that this product is expected to be miscible in hydrocarbons, including benzene, ether, and petroleum ether.

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  2. What do I do with the Product 256781, Diethylzinc, bottle once it is empty?

    1 answer
    1. Product 256781 is packed in a Sure/Pac cylinder. When the contents of the cylinder have been exhausted Sigma-Aldrich recommends that a licensed waste disposal company be contacted for the appropriate means to dispose of this container. Some residual product might remain in the container and should not be discarded with general waste. Alternatively, Sigma-Aldrich does offer an option for returning empty Sure/Pac cylinders. The customer will be required to pay for the return shipping and a minimal disposal charge, as Sigma-Aldrich does not require these cylinders to be returned. Additional information on the Sure/Pac return program can be obtained by contacting customer service at 800-325-3010.

      Helpful?

  3. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  4. How do I remove Product 256781, Diethylzinc, from the container?

    1 answer
    1. This product is air sensitive and is package under inert gas. Transfer of this product should be conducted under inert atmosphere (such as in a glove box or Atmosbag) to reduce the chance of exposure of the chemical to the atmosphere. Additional details about how to handle and store air-sensitive materials can be found in Sigma-Aldrich technical bulletin AL-134.

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