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395404

Sigma-Aldrich

Titan(IV)-chloridtetrahydrofuran-Komplex

97%

Synonym(e):

Titantetrachlorid Tetrahydrofuran-Komplex

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€ 80,50
25 G
€ 244,00

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5 G
€ 80,50
25 G
€ 244,00

About This Item

Lineare Formel:
TiCl4 · 2THF
CAS-Nummer:
Molekulargewicht:
333.89
MDL-Nummer:
UNSPSC-Code:
12352106
PubChem Substanz-ID:
NACRES:
NA.22

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Qualitätsniveau

Assay

97%

Eignung der Reaktion

core: titanium
reagent type: Lewis acid
reagent type: catalyst

mp (Schmelzpunkt)

126-128 °C (lit.)

Funktionelle Gruppe

ether

Lagertemp.

2-8°C

SMILES String

Cl[Ti](Cl)(Cl)Cl.C1CCOC1.C2CCOC2

InChI

1S/2C4H8O.4ClH.Ti/c2*1-2-4-5-3-1;;;;;/h2*1-4H2;4*1H;/q;;;;;;+4/p-4

InChIKey

LXWBMENBONGPSB-UHFFFAOYSA-J

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Allgemeine Beschreibung

Titanium(IV) chloride tetrahydrofuran complex, also known as TiCl4-THF, is a commonly used reagent in organic synthesis due to its Lewis acidic properties. It is used as a catalyst in various Friedel-Crafts reactions for the synthesis of aromatic compounds.

Anwendung

Titanium(IV) chloride tetrahydrofuran complex can be used as a catalyst in intermolecular hydroamination reactions.

Piktogramme

FlameCorrosion

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Flam. Sol. 1 - Skin Corr. 1B

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flammpunkt (°F)

1.4 °F - closed cup

Flammpunkt (°C)

-17 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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