If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
Über diesen Artikel
grade
synthesis grade
Quality Segment
vapor pressure
12 hPa ( 20 °C)
form
liquid
potency
3160 mg/kg LD50, skin (Rabbit)
bp
136 °C/1013 hPa
mp
-24 °C
density
1.728 g/cm3 at 20 °C
storage temp.
2-30°C
SMILES string
[Ti+4].[Cl-].[Cl-].[Cl-].[Cl-]
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
Application
- Ortho-Acylierung von Arylalkoholen für die Synthese der entsprechenden ortho-C-acylierten Produkte.
- Synthese von verschiedenen chlorierten Verbindungen mittels Baylis-Hillman-Reaktion von Arylaldehyden mit Methylvinylketon in Gegenwart einer Lewis-Base.
- Herstellung von 3,4-Dihydropyrimidin-2(1H)-onen und -thionen durch Biginelli-Kondensationsreaktion von Aldehyd, 1,3-Dicarbonylverbindung und Harnstoff oder Thioharnstoff.
- Hydrodefluorierungsreaktion in Gegenwart von Triethylsilan als Reduktionsmittel.
Analysis Note
Identität (ICP-OES): entspricht
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signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
hcodes
Lagerklasse
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
Analysenzertifikate (COA)
Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.
Besitzen Sie dieses Produkt bereits?
In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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How is it packed? A bottle with septum?
1 answer-
This product is provided in a glass bottle with a Teflon cap. It does not include a septum.
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