348295

4-Morpholincarbonsäurechlorid

98%

• Synonym(e): 4-Morpholincarbonylchlorid
• Empirische Formel (Hill-System): C₅H₈ClNO₂
• CAS-Nummer: 15159-40-7
• Molekulargewicht: 149.58
• Beilstein: 116257
• EG-Nummer: 239-213-0
• MDL-Nummer: MFCD00037053
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24861562
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: liquid
• Brechungsindex: n20/D 1.498 (lit.)
• bp: 137-138 °C/33 mmHg (lit.)
• Dichte: 1.282 g/mL at 25 °C (lit.)
• SMILES String: ClC(=O)N1CCOCC1
• InChI: 1S/C5H8ClNO2/c6-5(8)7-1-3-9-4-2-7/h1-4H2
• InChIKey: XMWFMEYDRNJSOO-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

4-Morpholinecarbonyl chloride is a photographic intermediate. Rates of solvolysis of 4-morpholinecarbonyl chloride with N-alkyl group in aqueous binary solvents of acetone, ethanol, methanol, methanol-d, 2,2,2-trifluoroethanol, pure water and D₂O has been determined. Preparation of 4-morpholinecarbonyl chloride has been reported.

Anwendung

4-Morpholinecarbonyl chloride may be used in the preparation of a versatile fluorogenic label for biomolecular imaging. It may be used in the synthesis of:

• morpholine-4-carboxylic acid [4-(2,4-dimethylphenyl)thiazol-2-yl]amide
• morpholine-4-carboxylic acid [4-(2,4,6-trimethylphenyl)thiazol-2-yl]amide
• 2-isopropyl-6-methylpyrimidin-4-yl morpholine-4-carboxylate

Sicherheitshinweise

• Piktogramme: GHS08,GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H351
• P-Sätze: P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Gefahreneinstufungen: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 235.4 °F - closed cup
• Flammpunkt (°C): 113 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter