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287717
Boranammoniak-Komplex
technical grade, 90%
Synonym(e):
Amin-Trihydrobor, Borazan
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1 G
€ 101,00
10 G
€ 213,00
About This Item
Lineare Formel:
H3N · BH3
CAS-Nummer:
Molekulargewicht:
30.87
MDL-Nummer:
UNSPSC-Code:
26111700
PubChem Substanz-ID:
NACRES:
NA.22
Empfohlene Produkte
Qualität
technical grade
Qualitätsniveau
Assay
90%
Form
solid
Eignung der Reaktion
reagent type: reductant
Grünere Alternativprodukt-Eigenschaften
Design for Energy Efficiency
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sustainability
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Grünere Alternativprodukt-Kategorie
SMILES String
B.N
InChI
1S/BH3.H3N/h2*1H3
InChIKey
WZMUUWMLOCZETI-UHFFFAOYSA-N
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Verwandte Kategorien
Allgemeine Beschreibung
Ammonia borane, also known as borazane has high hydrogen content (about 20% mass). Thermal decomposition of borazane takes place in the temperature range of 350-410K accompanied by hydrogen release and heat evolution. It may find use as a hydrogen source in fuel cells in the future.[1]
Borane-ammonia complex is a novel material, where ammonia is tightly bound to a ligand through all four of its atoms. It is a donor-acceptor complex that is formed by electron donation from a Lewis base (NH3) to a Lewis acid (BH3). It shows a B-N bond distance of 1.564 Å.[2][3]
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Anwendung
Mild, efficient, and stereoselective reducing agent for aldehydes and ketones in protic or nonprotic media.[4]
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Persönliche Schutzausrüstung
Eyeshields, Gloves
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Weng, B.; et al.
International Journal of Hydrogen Energy, 36, 10870-10870 (2011)
William C Ewing et al.
Journal of the American Chemical Society, 133(42), 17093-17099 (2011-10-04)
Studies of the activating effect of Verkade's base, 2,8,9-triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane (VB), on the rate and extent of H(2) release from ammonia borane (AB) have led to the syntheses and structural characterizations of three anionic aminoborane chain-growth products that provide direct support
Tetrahedron Letters, 693-693 (1980)
X. Yang, et al.,
Tetrahedron, 67, 7121-7127 (2011)
Ab initio/GIAO-CCSD (T) study of the effects of protonation on borane-ammonia (H3BNH3) and related complexes
Rasul G, et al.
Journal of Molecular Structure: THEOCHEM, 818(1-3), 65-70 (2007)
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