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283606

Sigma-Aldrich

Palladium(II)-chlorid -Lösung

5 wt. % in 10 wt. % HCl

Synonym(e):

Dichloropalladium, Palladium dichloride, Palladous chloride

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About This Item

Lineare Formel:
PdCl2
CAS-Nummer:
Molekulargewicht:
177.33
MDL-Nummer:
UNSPSC-Code:
12161600
PubChem Substanz-ID:
NACRES:
NA.22

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Form

liquid

Qualitätsniveau

Eignung der Reaktion

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Konzentration

5 wt. % in 10 wt. % HCl

Dichte

1.06 g/mL at 25 °C

SMILES String

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChIKey

PIBWKRNGBLPSSY-UHFFFAOYSA-L

Allgemeine Beschreibung

Palladium(II) chloride is a representative salt of Pd(II) that is used as a precursor to prepare palladium catalysts for various reactions, such as Heck coupling, Suzuki coupling, Sonagashira coupling, and Buchwald-Hartwig coupling. It is also used as an oxidizing agent.

Anwendung

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.[1]

Signalwort

Danger

Gefahreneinstufungen

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

Lagerklassenschlüssel

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
Gábor Kovács et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(18), 5612-5619 (2012-03-31)
First-principles molecular dynamics coupled with metadynamics have been used to gain a deeper insight into the reaction mechanism of the Wacker process by determining the nature of the active species. An explicit and dynamic representation of the aqueous solvent, which
Maria Elisabete Machado et al.
Journal of chromatography. A, 1274, 165-172 (2013-01-10)
The separation of the organic sulfur compounds (OSC) of petroleum or its heavy fractions is a critical step and is essential for the correct characterization of these compounds, especially due to similar physical and chemical properties of polycyclic aromatic sulfur
Feng-Quan Yuan et al.
Chemical communications (Cambridge, England), 47(18), 5289-5291 (2011-04-01)
We present a PdCl(2)-catalyzed protocol for highly efficient allylation and benzylation of a rich variety of N-, O-, and S-containing heteroarenes under base/acid, additive, and ligand-free conditions. The method represents the very few examples for simple, universally applicable, clean, and
Chun Liu et al.
Organic & biomolecular chemistry, 9(4), 1054-1060 (2010-12-15)
A simple and efficient protocol has been developed for the PdCl(2)-catalyzed ligand-free and aerobic Suzuki reaction of aryl bromides or nitrogen-based heteroaryl bromides with arylboronic acids in good to excellent yields in aqueous ethanol. A systematic investigation on the effect

Questions

  1. Does the 5 wt. % in 10 wt. % HCl mean PdCl2 weight percent or just the Pd weight percent? i.e if the solution weight is 100g, is the mass of Pd 5g or mass of PdCl2 5g?

    1 answer
    1. 5 wt% is the weight of PdCl2. If the solution weight is 100g, the mass of PdCl2 is 5g.

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