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重要文件

185302

Sigma-Aldrich

二异丙基醚

ReagentPlus®, 99%, contains either BHT or hydroquinone as stabilizer

同義詞:

异丙醚

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About This Item

線性公式:
(CH3)2CHOCH(CH3)2
CAS號碼:
分子量::
102.17
Beilstein:
1731256
EC號碼:
MDL號碼:
分類程式碼代碼:
12191502
PubChem物質ID:
NACRES:
NA.07
bp:
68-69 °C (lit.)
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等級

reagent

品質等級

蒸汽密度

3.5 (vs air)

蒸汽壓力

120 mmHg ( 20 °C)

產品線

ReagentPlus®

化驗

99%

形狀

liquid

自燃溫度

827 °F

expl. lim.

1-21 %, 100 °F

dilution

(for general lab use)

折射率

n20/D 1.367 (lit.)

bp

68-69 °C (lit.)

mp

−85 °C (lit.)

密度

0.725 g/mL at 25 °C (lit.)

SMILES 字串

CC(C)OC(C)C

InChI

1S/C6H14O/c1-5(2)7-6(3)4/h5-6H,1-4H3

InChI 密鑰

ZAFNJMIOTHYJRJ-UHFFFAOYSA-N

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一般說明

Diisopropyl ether is a colorless liquid. It is widely used as a solvent for the isolation of fats and oils. It can be synthesized from isopropyl alcohol. Its mixture with isooctane has been added to the gasoline fuel as an antiknocking agent.[1] Its synthesis from propylene and water in a single-pass trickle-bed reactor in the presence of an ion-exchange resin catalyst Amberlyst 15 has been proposed.[2] Its efficacy as a fuel additive has been reported. When released in the atmosphere, it undergoes photodecomposition by reacting with OH radicals. Kinetics and mechanism of its reaction in atmosphere have been reported.[3]

應用

Diisopropyl ether may be employed as a solvent for the preparation of aliphatic and aromatic cyanohydrins.[4]

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形圖

FlameExclamation mark

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 2 - STOT SE 3

標靶器官

Central nervous system

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

-20.2 °F - closed cup

閃點(°C)

-29 °C - closed cup


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存取文件庫

Atmospheric chemistry of automotive fuel additives: diisopropyl ether.
Wallington TJ, et al.
Environmental Science & Technology, 27(1), 98-104 (1993)
Single stage synthesis of diisopropyl ether-an alternative octane enhancer for lead-free petrol.
Heese FP, et al.
Catalysis Today, 49(1), 327-335 (1999)
Novel (R)-oxynitrilase sources for the synthesis of (R)-cyanohydrins in diisopropyl ether.
Kiljunen E and Kanerva LT.
Tetrahedron Asymmetry, 8(8), 1225-1234 (1997)
Eagleson M.
Concise Encyclopedia Chemistry, 325-325 (1994)
I Linhart et al.
Toxicology and applied pharmacology, 136(1), 155-160 (1996-01-01)
Biotransformation of acrolein (ACR) was studied in vivo in the rat following inhalation and ip administration. The major and minor urinary metabolites were 3-hydroxypropylmercapturic acid (HPMA) and 2-carboxyethylmercapturic acid (CEMA), respectively. Male Wistar rats were exposed to ACR, 23, 42

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