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Merck
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重要文件

30552

Supelco

莫能菌素甲酯

Selectophore, ≥97.0% (TLC)

同義詞:

甲基莫能菌素酯

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About This Item

經驗公式(希爾表示法):
C37H64O11
CAS號碼:
分子量::
684.90
Beilstein:
3641733
MDL號碼:
分類程式碼代碼:
26111700
NACRES:
NB.61
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等級

for ion-selective electrodes

品質等級

產品線

Selectophore

化驗

≥97.0% (TLC)

儲存溫度

2-8°C

SMILES 字串

CC[C@]1(CCC(O1)[C@]2(C)CC[C@]3(C[C@H](O)[C@@H](C)C(O3)[C@@H](C)[C@@H](OC)[C@H](C)C(=O)OC)O2)C4OC(C[C@@H]4C)C5O[C@@](O)(CO)[C@H](C)C[C@@H]5C

InChI

1S/C37H64O11/c1-11-35(32-21(3)17-27(44-32)29-20(2)16-22(4)37(41,19-38)47-29)13-12-28(45-35)34(8)14-15-36(48-34)18-26(39)23(5)31(46-36)24(6)30(42-9)25(7)33(40)43-10/h20-32,38-39,41H,11-19H2,1-10H3/t20-,21+,22+,23+,24+,25+,26-,27-,28+,29-,30-,31-,32-,34+,35-,36+,37-/m0/s1

InChI 密鑰

PFRZSHIENRKVSE-RJTHVKINSA-N

一般說明

Monensin, is an antibiotic produced by Streptomyces cinnamonensis.[1] It is a naturally occurring ionophore. It has an acyclic polyether sequence and a terminal carboxylic acid moiety.[2] It has the ability to effectively carry protons and cations through the cell membrane[3], hence it adequately harbours Na+ into a characteristic pseudoactivity, thereby effectively transporting it across a bio-membrane. It also forms stable complexes with k+, Rb+ and Ag+; hence it can be chemically modified to form cation-binding sites, thereby attaining transport functionalities.[2]
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應用


  • The selectivity of membrane ion-selective electrodes: This research explores the use of temperature variations to adjust the selectivity of ion-selective electrodes, utilizing Monensin methyl ester as a key component for sodium ion detection (Zahran et al., 2010).

  • Spectroscopic and semiempirical studies of a proton channel formed by the methyl ester of monensin A.: This paper presents a detailed analysis of the proton channel properties of Monensin methyl ester through spectroscopic and computational methods, highlighting its potential in analytical chemistry applications (Huczyński et al., 2006).

  • Ion chromatography detector based on solid-state ion-selective electrode array.: The development of an ion chromatography detector employing solid-state ion-selective electrodes, with Monensin methyl ester playing a crucial role in sodium ion detection, is detailed in this study (Lee et al., 2000).

包裝

Bottomless glass bottle. Contents are inside inserted fused cone.

法律資訊

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Oral

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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José N Sousa et al.
European journal of mass spectrometry (Chichester, England), 13(3), 191-198 (2007-09-21)
This paper reports the first comparative study of the gas-phase fragmentation chemistry of monensin in negative ion mode electrospray and nanoelectrospray tandem mass spectrometry. The fragmentation was observed to occur at lower energies in nanoelectrospray than electrospray. The major product
Adam Huczyñski et al.
The journal of physical chemistry. B, 110(31), 15615-15623 (2006-08-04)
Monensin A is an ionophore able to carry protons and cations through the cell membrane. Its methyl ester (MON1) and its hydrates have been studied in acetonitrile, and its deuterated analogue by Fourier transform infrared (FTIR) and (1)H and (13)C
Specific Ag+ ion-transport properties of functionalized biological monensin ionophore.
Tsukube H and Sohmiya H.
Inorgorganica Chimica Acta, 166 (1), 27-29 (1989)
Zum Funktionsprinzip von Elektrodenmembranen mit dem Carboxyl-Ionophoren Monensin an Festkontaktsensoren
J.G. Schindler , M.M. Schindler
Fresenius Journal of Analytical Chemistry, 332, 52-57 (1988)
Spectroscopic and semiempirical studies of a proton channel formed by the methyl ester of monensin A.
Huczynski A
The Journal of Physical Chemistry B, 110 (31), 15615-15623 (2006)

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