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905100

Ir(p-tBu-ppy)₃

Name: Ir(<I>p</I>-tBu-ppy)<SUB>3</SUB>
Brand: ALDRICH

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About This Item

經驗公式（希爾表示法）:

C₄₅H₄₈IrN₃

CAS號碼:

1396451-04-9

分子量：:

823.10

分類程式碼代碼:

12352101

NACRES:

NA.22

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747793

(Ir[dF(CF₃)ppy]₂(dtbpy))PF₆

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904694

Ir(p-CF₃-ppy)₃

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688096

三[2-苯基吡啶-C²,N]铱(III)

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747769

[Ir(dtbbpy)(ppy)₂]PF₆

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754730

三（2,2′-联吡啶）钌（II）六氟磷酸盐

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915297

4CzIPN

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900570

Ir[dF(t-Bu)-ppy]₃

Sigma-Aldrich

900538

Ir(p-F-ppy)₃

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901409

[铱 (dF (Me) ppy)] ₂ (dtbbpy) ] PF ₆

Sigma-Aldrich

544981

三（2,2′——联吡啶二氯钌 (II) 六水合物

形狀

powder

反應適用性

reaction type: Photocatalysis
reagent type: catalyst

應用

This photocatalyst facilitates a variety of transformations using visible light, including the benzylation of aldehydes with alcohols.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析證明 (COA)

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Visible-Light Photocatalytic Decarboxylation of α,β-Unsaturated Carboxylic Acids: Facile Access to Stereoselective Difluoromethylated Styrenes in Batch and Flow.

Xiao-Jing Wei et al.

ACS catalysis, 7(10), 7136-7140 (2017-11-08)

The development of synthetic methodologies which provide access to both stereoisomers of α,β-disubstituted olefins is a challenging undertaking. Herein, we describe the development of an operationally simple and stereoselective synthesis of difluoromethylated styrenes via a visible-light photocatalytic decarboxylation strategy using

Spin-Center Shift-Enabled Direct Enantioselective α-Benzylation of Aldehydes with Alcohols.

Eric D Nacsa et al.

Journal of the American Chemical Society, 140(9), 3322-3330 (2018-02-06)

Nature routinely engages alcohols as leaving groups, as DNA biosynthesis relies on the removal of water from ribonucleoside diphosphates by a radical-mediated "spin-center shift" (SCS) mechanism. Alcohols, however, remain underused as alkylating agents in synthetic chemistry due to their low

Photocatalytic Generation of 2-Azolyl Radicals: Intermediates for the Azolylation of Arenes and Heteroarenes via C-H Functionalization.

Amandeep Arora et al.

Organic letters, 18(16), 3996-3999 (2016-08-06)

The 2-azolyl radical, generated from 2-bromoazoles via photocatalysis, is a powerful intermediate for the intermolecular arylation of unmodified (hetero)arenes. The reaction is characterized by mild conditions, operational simplicity, tolerance toward functional and sterically demanding groups, broad scope, and anti-Minisci selectivity.

Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis

Singh A, et al.

Journal of Organometallic Chemistry, 776, 51-59 (2015)

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