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Merck

208361

Sigma-Aldrich

四氟硼酸银

98%

别名:

氟硼酸银

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1 G
$58.10
10 G
$175.00
50 G
$835.00

About This Item

线性分子式:
AgBF4
CAS号:
分子量:
194.67
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

$58.10


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方案

98%

反应适用性

core: silver
reagent type: catalyst

mp

70-73 °C (lit.)

SMILES字符串

[Ag+].F[B-](F)(F)F

InChI

1S/Ag.BF4/c;2-1(3,4)5/q+1;-1

InChI key

CCAVYRRHZLAMDJ-UHFFFAOYSA-N

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一般描述

四氟硼酸银(AgBF4)在有机合成中被用作路易斯酸。它对有机卤化物有很高的亲和性。它可用于酰氯的活化、亲核取代、重排、环加成、环化、环扩张、氧化等有机反应。[1]

应用

在过硫酸盐氧化醇的过程中,从贵金属配合物中置换氯离子。[2]
提供银离子模板,改善线性二肽的macrolatamization 。[3]

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

J. Mol. Catal., 79, 85-85 (1993)
Kende, A. S.; Huang, H.
Tetrahedron Letters, 38, 3353-3353 (1997)
Silver tetrafluoroborate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2005)
Silver tetrafluoroborate
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2005)
Synlett, 1901-1901 (2007)

商品

Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.

相关内容

The importance of selectively fluorinating compounds in medicinal chemistry, biology, and organic synthesis is well appreciated and provides a major impetus to the discovery of new and mild fluorinating agents that can operate safely and efficiently.

We are proud to offer a treasure-trove of gold precatalysts and silver salts, as well as an extensive portfolio of unsaturated building blocks to accelerate your research success in this exciting field.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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