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Merck
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文件

227722

Sigma-Aldrich

六氟磷酸银

98%

别名:

Silver(I) hexafluorophosphate

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About This Item

线性分子式:
AgPF6
CAS号:
26042-63-7
分子量:
252.83
EC號碼:
247-428-6
MDL號碼:
MFCD00003415
分類程式碼代碼:
12161600
PubChem物質ID:
24853649
NACRES:
NA.22

化驗

98%

形狀

solid

反應適用性

core: silver
reagent type: catalyst

mp

102 °C (dec.) (lit.)

SMILES 字串

[Ag+].F[P-](F)(F)(F)(F)F

InChI

1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1

InChI 密鑰

SCQBROMTFBBDHF-UHFFFAOYSA-N

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相关类别

一般說明

六氟磷酸银可作为催化剂用于硫酰亚胺化（sulfimidation）、醛氢化转化为醇以及炔烃和羧酸的氢酰氧基化（hydroacyloxylation）。

應用

（六氟锑酸银）用于制备3,3′-二氰基二苯基乙炔银配位网络，以研究配体对网络结构的作用，以便研制新型材料。（六氟锑酸银）可制备银配合物的超分子网络。

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

分析证书(COA)

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Gold (I)-catalyzed addition of carboxylic acids to alkynes
Chary B, et al.
The Journal of Organic Chemistry, 75, 7928-7931 (2010)
Silver-Catalyzed Enantioselective Sulfimidation Mediated by Hydrogen Bonding Interactions
Annapureddy R, et al.
Angewandte Chemie (International Edition in English), 133, 7999-8005 (2021)
Silver-Catalyzed Hydrogenation of Aldehydes in Water
Jia Z, et al.
Angewandte Chemie (International Edition in English), 52, 11871-11874 (2013)
Journal of Organometallic Chemistry, 692, 4093-4093 (2007)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

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