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Merck

227730

Sigma-Aldrich

六氟锑酸银

98%

别名:

Silver hexafluoroantimony, Silver hexafluorostiboranuide

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1 G
$78.00
5 G
$160.00
25 G
$661.00

About This Item

线性分子式:
AgSbF6
CAS号:
分子量:
343.62
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

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质量水平

方案

98%

表单

powder

反应适用性

reagent type: catalyst
core: silver

SMILES字符串

[Ag+].F[Sb-](F)(F)(F)(F)F

InChI

1S/Ag.6FH.Sb/h;6*1H;/q+1;;;;;;;+5/p-6

InChI key

GSXFODUDOAXUBF-UHFFFAOYSA-H

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应用

可形成稳定的阳离子自由基盐[1][2],并作为环氧化物开环反应[3]和亚磺酰化反应的酸性催化剂。[4]用于制备 3,3′-二氰基二苯基乙炔银配位网络,以研究配体对网络结构的作用,以便研制新型材料。[5]

象形图

Exclamation markEnvironment

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2

储存分类代码

8B - Non-combustible corrosive hazardous materials

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chemistry Letters (Jpn), 1901-1901 (1992)
Development of a Nazarov cyclization/Wagner-Meerwein rearrangement sequence for the stereoselective synthesis of spirocycles.
Jie Huang et al.
Journal of the American Chemical Society, 129(26), 8060-8061 (2007-06-09)
The Journal of Organic Chemistry, 57, 6178-6178 (1992)
Chemistry Letters (Jpn), 1-1 (1993)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

商品

Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.

Plasmonic nanoparticles have unique optical properties that can be tailored to suit a variety of applications in the biotechnology1–8 and electronics9–16 industries.

相关内容

The importance of selectively fluorinating compounds in medicinal chemistry, biology, and organic synthesis is well appreciated and provides a major impetus to the discovery of new and mild fluorinating agents that can operate safely and efficiently.

We are proud to offer a treasure-trove of gold precatalysts and silver salts, as well as an extensive portfolio of unsaturated building blocks to accelerate your research success in this exciting field.

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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