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Merck
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文件

515884

Sigma-Aldrich

三氟甲磺酸铝

99.9% trace metals basis

别名:

三（三氟甲烷）铝, 三（三氟甲磺酸铝）铝, 三(三氟磺酸)铝

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About This Item

线性分子式:
(CF3SO3)3Al
CAS号:
74974-61-1
分子量:
474.19
MDL號碼:
MFCD00143596
分類程式碼代碼:
12161600
PubChem物質ID:
24873851
NACRES:
NA.22

化驗

99.9% trace metals basis

反應適用性

core: aluminum
reagent type: catalyst

mp

300 °C (lit.)

SMILES 字串

[Al+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/3CHF3O3S.Al/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3

InChI 密鑰

FKOASGGZYSYPBI-UHFFFAOYSA-K

相关类别

應用

三氟甲磺酸铝 (三氟磺酸铝或Al(OTf)3) 可用作以下反应的催化剂：
  • 通过不饱和醇的环化异构化进行环醚的区域选择性合成。
  • 糖类转化为5-羟甲基糠醛 (5-HMF)。
  • 与Pd(OAc)2/BINAP 一起参与苯乙炔的甲氧羰基化反应。

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Recyclable Pd (OAc) 2/Ligand/Al (OTf) 3 Catalyst for the Homogeneous Methoxycarbonylation and Hydrocarboxylation Reactions of Phenylacetylene
Williams DBG, et al.
Organometallics, 30(18), 4968-4973 (2011)
Aluminium (III) trifluoromethanesulfonate as an efficient catalyst for the intramolecular hydroalkoxylation of unactivated olefins: experimental and theoretical approaches
Coulombel L, et al.
Chemistry?A European Journal , 12(24), 6356-6365 (2006)
Valorization of an underused sugar derived from hemicellulose: Efficient synthesis of 5-hydroxymethylfurfural from mannose with aluminum salt catalyst in dimethyl sulfoxide/water mixed solvent
Jia S, et al.
Royal Society of Chemistry Advances, 7(62), 39221-39227 (2017)
Shaochen Zhang et al.
Science (New York, N.Y.), 364(6435), 45-51 (2019-04-06)
Accessing enantiomerically enriched amines often demands oxidation-state adjustments, protection and deprotection processes, and purification procedures that increase cost and waste, limiting applicability. When diastereomers can be formed, one isomer is attainable. Here, we show that nitriles, largely viewed as insufficiently
B V Subba Reddy et al.
Organic letters, 15(3), 464-467 (2013-01-18)
A novel method has been devised for the synthesis of 2,4,5-trisubstituted pyrrole derivatives through the coupling of α-diazoketones with β-enaminoketones and esters using 10 mol % of Cu(OTf)(2). A wide range of 2,3-disubstituted indole derivatives were also prepared from α-diazoketones
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