794287

Bis[(pinacolato)boryl]methane

• Synonym(e): 2,2′-Methylenebis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane], Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methane
• Empirische Formel (Hill-System): C₁₃H₂₆B₂O₄
• CAS-Nummer: 78782-17-9
• Molekulargewicht: 267.97
• MDL-Nummer: MFCD27977747
• UNSPSC-Code: 12352200
• PubChem Substanz-ID: 329768437
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 100
• Grünere Alternativprodukt-Eigenschaften: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp (Schmelzpunkt): 48 °C
• Grünere Alternativprodukt-Kategorie: Aligned,
• Lagertemp.: 2-8°C
• SMILES String: CC(C(C)(C)O1)(C)OB1CB2OC(C)(C)C(C)(C)O2
• InChI: 1S/C13H26B2O4/c1-10(2)11(3,4)17-14(16-10)9-15-18-12(5,6)13(7,8)19-15/h9H2,1-8H3
• InChIKey: MQYZGGWWHUGYDR-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Bis[(pinacolato)boryl]methane is an aryl boronate ester.

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Anwendung

Bis-boronate has been reported by Morken and coworkers to be a key building block in the synthesis of enantioenriched secondary boronate esters, which undergo facile Suzuki-Miyaura coupling with minimal erosion of enantiopurity.

Bis[(pinacolato)boryl]methane may be used in the preparation of trans-vinyl boronate esters, via the Boron-Wittig reaction.

Sonstige Hinweise

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3