728551
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
≥97% (AT)
동의어(들):
Chloro[N2-[2-(dimethylamino-κN)phenyl]-N1,N1-dimethyl-1,2-benzenediaminato-κN1,κN2]-nickel, Nickamine
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모든 사진(1)
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100 MG
₩519,274
500 MG
₩1,213,940
About This Item
실험식(Hill 표기법):
C16H20ClN3Ni
CAS Number:
Molecular Weight:
348.50
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22
추천 제품
분석
≥97% (AT)
양식
lumps
반응 적합성
core: nickel
reagent type: catalyst
SMILES string
CN(C)c1ccccc1N([Ni]Cl)c2ccccc2N(C)C
InChI
1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1
InChI key
IRLHVNUEEKJBEL-UHFFFAOYSA-M
애플리케이션
Catalyst for:
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
- Alkyl-alkyl Kumada coupling of secondary alkyl halides
- Direct alkylation of heterocyclic C-H bonds
- Sonogashira coupling of nonactivated alkyl halides
- Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
포장
Bottomless glass bottle. Contents are inside inserted fused cone.
관련 제품
제품 번호
설명
가격
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
가장 최신 버전 중 하나를 선택하세요:
시험 성적서(COA)
Lot/Batch Number
이미 열람한 고객
![[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)](/deepweb/assets/sigmaaldrich/product/structures/844/065/af07f787-c6a3-4a6e-a22b-47a933c73978/640/af07f787-c6a3-4a6e-a22b-47a933c73978.png)
Oleg Vechorkin et al.
Angewandte Chemie (International ed. in English), 48(16), 2937-2940 (2009-01-29)
Reacting in the 'Ni'ck of time: The title reaction is realized by using an isolated Ni(II) complex (1). The catalysis tolerates a wide range of important functional groups that are often incompatible with Grignard reagents in cross-coupling reactions.
Zsolt Csok et al.
Journal of the American Chemical Society, 130(26), 8156-8157 (2008-06-06)
A new pincer-type bis(amino)amine (NN2) ligand and its lithium and nickel complexes, including Ni(II) methyl, ethyl, and phenyl complexes, were synthesized. The Ni(II) alkyl complexes react cleanly with alkyl halides including chlorides to form C-C coupled products and Ni(II) halides.
문서
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
활성 필터
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
고객지원팀으로 연락바랍니다.
