713694

(S)-(−)-2′-Amino-1,1′-binaphthalen-2-ol

97%

• 동의어(들): (S)-(−)-2-Amino-2′-hydroxy-1,1′-binaphthalene, (S)-NOBIN
• 실험식(Hill 표기법): C₂₀H₁₅NO
• CAS Number: 137848-29-4
• Molecular Weight: 285.34
• MDL number: MFCD01882346
• UNSPSC 코드: 12352005
• PubChem Substance ID: 329763211
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: ≥96.5% (HPLC); 97%
• 형태: crystals
• 광학 순도: enantiomeric excess: ≥98.0%
• InChI: 1S/C20H15NO/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,22H,21H2
• InChI key: HIXQCPGXQVQHJP-UHFFFAOYSA-N

설명

애플리케이션

(S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol or (S)-NOBIN, is a non-symmetrically substituted 1,1′-binaphthalene ligand. It can be used as a catalyst in the asymmetric synthesis of unnatural α-alkyl amino acids by phase-transfer catalysis (PTC). (S)-NOBIN can also be employed as starting material to prepare N-monoalkyl and N,N-dialkyl (S)-NOBIN analogs by reacting with aldehydes via reductive amination reaction. N-monoaryl derivatives are obtained from NOBIN via Hartwig−Buchwald arylation reaction.

포장

Bottomless glass bottle. Contents are inside inserted fused cone.

안전성 정보

• 픽토그램: GHS05,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H318,H410
• 예방조치 성명서: P273 - P280 - P305 + P351 + P338 - P501
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves