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Merck
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주요 문서

60811

Sigma-Aldrich

Cobalt carbonyl

moistened with hexane (hexane 1-10%), ≥90% (Co)

동의어(들):

Cobalt tetracarbonyl dimer, Di-μ-carbonylhexacarbonyldicobal, Octacarbonyldicobalt, Dicobalt octacarbonyl

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크기 선택

5 G
₩287,651
25 G
₩637,522

₩287,651


출고 가능일2025년 4월 15일세부사항


벌크 견적 요청

크기 선택

보기 변경
5 G
₩287,651
25 G
₩637,522

About This Item

Linear Formula:
Co2(CO)8
CAS Number:
Molecular Weight:
341.95
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

₩287,651


출고 가능일2025년 4월 15일세부사항


벌크 견적 요청

Quality Level

분석

≥90% (Co)

양식

solid

품질

moistened with hexane (hexane 1-10%)

반응 적합성

core: cobalt
reagent type: catalyst

저장 온도

2-8°C

SMILES string

[Co++].[Co++].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/8CO.2Co/c8*1-2;;/q;;;;;;;;2*+2

InChI key

MQIKJSYMMJWAMP-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

애플리케이션

  • Cobalt carbonyl [Co2(CO)8] is commonly used as a catalyst in the hydroformylation (oxo reaction) of alkenes.[1][2]
  • Along with pyridine, it can be used as a catalyst in the carboxylation of alkenes into corresponding acids and esters.[1]
  • It is employed as a key precursor in the preparation of cobalt platinum (CoPt3), cobalt sulfide (Co3S4) and cobalt selenide (CoSe2) nanocrystals.[3][4]
  • It is also used as a reagent in Pauson-Khand cyclizations and Nicholas reaction.[5][6]

픽토그램

FlameSkull and crossbonesHealth hazard

신호어

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Repr. 2 - Self-heat. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Inhalation

표적 기관

Nervous system

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point (°F)

-9.4 °F

Flash Point (°C)

-23 °C

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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시험 성적서(COA)

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이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

A Lewis acid-mediated version of the Nicholas reaction: Synthesis of syn-alkylated products and cobalt-complexed cycloalkynes.
Schreiber SL, et al.
Journal of the American Chemical Society, 108(11), 3128-3130 (1986)
M Varón et al.
Scientific reports, 3, 1234-1234 (2013-02-08)
Magnetostatic (dipolar) interactions between nanoparticles promise to open new ways to design nanocrystalline magnetic materials and devices if the collective magnetic properties can be controlled at the nanoparticle level. Magnetic dipolar interactions are sufficiently strong to sustain magnetic order at
In situ free-surfactant synthesis and ORR-electrochemistry of carbon-supported Co3S4 and CoSe2 nanoparticles.
Feng Y, et al.
Chemistry of Materials, 20(1), 26-28 (2007)
Octacarbonyldicobalt.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-26 (2014)
Eirini Zacharaki et al.
Chemistry Central journal, 10, 10-10 (2016-03-10)
Reproducible growth of narrow size distributed ε-Co nanoparticles with a specific size requires full understanding and identification of the role of essential synthesis parameters for the applied synthesis method. For the hot injection methodology, a significant discrepancy with respect to

문서

Magnetic nanoparticles have attracted tremendous attention due to their novel properties and their potential applications in magnetic recording, magnetic energy storage and biomedicine.

Ultrasonic spray pyrolysis produces scalable nanomaterials like metal oxides and quantum dots for diverse applications.

질문

1–3 / 3 질문  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 답변
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 답변
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. Is this packed under inert gas?

    1 답변
    1. Yes, this product is packaged under an inert gas as a precautionary measure. Additionally, since it is sensitive to air, it should be handled and stored under an inert gas.

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