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Merck
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주요 문서

195731

Sigma-Aldrich

Iron(0) pentacarbonyl

greener alternative

동의어(들):

Iron(0) carbonyl, Pentacarbonyliron(0)

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크기 선택

50 G
₩137,533
250 G
₩346,927
1 KG
₩776,983

₩137,533


구입 가능 여부는 고객센터에 문의하십시오.

벌크 견적 요청

크기 선택

보기 변경
50 G
₩137,533
250 G
₩346,927
1 KG
₩776,983

About This Item

Linear Formula:
Fe(CO)5
CAS Number:
Molecular Weight:
195.90
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

₩137,533


구입 가능 여부는 고객센터에 문의하십시오.

벌크 견적 요청

vapor density

6.74 (vs air)

Quality Level

vapor pressure

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

autoignition temp.

122 °F

반응 적합성

core: iron
reagent type: catalyst

환경친화적 대안 제품 특성

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

refractive index

n20/D 1.5196 (lit.)

bp

103 °C (lit.)

mp

−20 °C (lit.)

density

1.49 g/mL at 25 °C (lit.)

환경친화적 대안 카테고리

저장 온도

2-8°C

SMILES string

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.Fe/c5*1-2;

InChI key

FYOFOKCECDGJBF-UHFFFAOYSA-N

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일반 설명

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

애플리케이션

Iron(0) pentacarbonyl can be used:
  • As an iron source to synthesize Fe-doped thin TiO2 films.[1]
  • As a ligand to synthesize complexes of gold(I) and Fe(CO)5,[2] silver and Fe(CO)5.[3]
Reactant for:
  • Addition reactions
  • Decomposition via photolysis
  • Preparation of magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution via thermal decomposition
  • Preparation of a heptanuclear iron carbonyl cluster used in catalytic hydrosilane reduction of carboxamides

  • Precursor for preparation of Fe nanoparticles for photocatalytic hydrogen evolution under highly basic conditions

픽토그램

FlameSkull and crossbones

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

5.0 °F - closed cup

Flash Point (°C)

-15 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

Bianca Seminotti et al.
International journal of developmental neuroscience : the official journal of the International Society for Developmental Neuroscience, 26(7), 693-698 (2008-08-12)
The present work investigated the in vitro effects of lysine on important parameters of oxidative stress in cerebral cortex of young rats. Our results show that lysine significantly induced lipid peroxidation, as determined by increase of thiobarbituric acid-reactive substances and
S Lakshmi Devi et al.
Amino acids, 38(3), 869-879 (2009-04-22)
Taurine effectively prevents ischemia-induced apoptosis in the cardiomyocytes and hypothalamic nuclei. The present study explores the influence of taurine on mitochondrial damage, oxidative stress and apoptosis in experimental liver fibrosis. Male albino Wistar rats were divided into six groups and
Victoria N Tsupreva et al.
Inorganic chemistry, 50(8), 3325-3331 (2011-03-17)
Interaction of the copper, {[3,5-(CF(3))(2)Pz]Cu}(3), and silver, {[3,5-(CF(3))(2)Pz]Ag}(3), macrocycles [3,5-(CF(3))(2)Pz = 3,5-bis(trifluoromethyl)pyrazolate] with cyclooctatetraeneiron tricarbonyl, (cot)Fe(CO)(3), was investigated by IR and NMR spectroscopy for the first time. The formation of 1:1 complexes was observed at low temperatures in hexane. The
Anders Bergh et al.
Carbohydrate research, 343(10-11), 1808-1813 (2008-05-13)
Cationic iron carbonyl cyclohexadiene complexes were employed in the derivatization of the 3-OH position of unprotected and protected methyl beta-D-galactopyranosides using two different approaches, giving access to galactopyranosides with an aromatic or cyclohexadienoic functionality in this position.
John T Tsalavoutis et al.
Journal of computational chemistry, 31(10), 1969-1978 (2010-01-21)
The equilibrium structures and vibrational frequencies of the iron complexes [Fe(0)(CN)(n)(CO)(5-n)](n-) and [Fe(II)(CN)(n)(CO)(5-n)](2-n) (n = 0-5) have been calculated at the BP86 level of theory. The Fe(0) complexes adopt trigonal bipyramidal structures with the cyano ligands occupying the axial positions

질문

1–3 / 3 질문  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 답변
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 답변
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. Qual è il grado di purezza?

    1 답변
    1. This product is not tested for purity and is considered a general use item. Should the purity and additional analytical testing be required, see product 481718. A link to this product page, as well as a sample Certificate of Analysis are provided below:

      481718 Iron(0) Pentacarbonyl product page:
      https://www.sigmaaldrich.com/US/en/product/aldrich/481718

      Sample Certificate of Analysis:
      https://www.sigmaaldrich.com/certificates/sapfs/PROD/sap/certificate_pdfs/COFA/Q14/481718-BULKSHBQ5322.pdf

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