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Merck
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주요 문서

481718

Sigma-Aldrich

Iron(0) pentacarbonyl

greener alternative

>99.99% trace metals basis

동의어(들):

Iron(0) carbonyl, Pentacarbonyliron(0)

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크기 선택

25 ML
₩180,467
100 ML
₩338,706

₩180,467


예상 입고일2025년 4월 21일세부사항


벌크 견적 요청

크기 선택

보기 변경
25 ML
₩180,467
100 ML
₩338,706

About This Item

Linear Formula:
Fe(CO)5
CAS Number:
Molecular Weight:
195.90
EC Number:
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.23

₩180,467


예상 입고일2025년 4월 21일세부사항


벌크 견적 요청

vapor density

6.74 (vs air)

Quality Level

vapor pressure

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

분석

>99.99% trace metals basis

양식

liquid

autoignition temp.

122 °F

반응 적합성

core: iron
reagent type: catalyst

환경친화적 대안 제품 특성

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

refractive index

n20/D 1.5196 (lit.)

bp

103 °C (lit.)

mp

−20 °C (lit.)

density

1.49 g/mL at 25 °C (lit.)

환경친화적 대안 카테고리

저장 온도

2-8°C

SMILES string

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.Fe/c5*1-2;

InChI key

FYOFOKCECDGJBF-UHFFFAOYSA-N

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일반 설명

Iron(0) pentacarbonyl is a straw-yellow to brilliant orange liquid soluble in organic solvents. It is widely used as a precursor for synthesizing iron oxide nanoparticles, which have applications in the field of energy conversion and storage due to their catalytic properties and ability to enhance electron transport.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

애플리케이션

Iron(0) pentacarbonyl can be used:
  • To fabricate Fe-based anode materials for high-performance aqueous secondary Ni−Fe batteries. It helps to achieve good safety, high power density, long term-life cycle, and high energy density.
  • As a precursor to synthesize highly stable, colloidal magnetic iron nanoparticles with narrow size distribution. These nanoparticles are potential candidates for MRI contrasting agents and magnetically separable catalysts.
  • To synthesize zero valent sustainable iron nanocatalysts for reduction reactions.

Reactant for:
  • Addition reactions
  • Decomposition via photolysis
  • Preparation of magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution via thermal decomposition
  • Preparation of a heptanuclear iron carbonyl cluster used in catalytic hydrosilane reduction of carboxamides

  • Precursor for preparation of Fe nanoparticles for photocatalytic hydrogen evolution under highly basic conditions

픽토그램

FlameSkull and crossbones

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

5.0 °F - closed cup

Flash Point (°C)

-15 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number

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이 제품을 이미 가지고 계십니까?

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문서 라이브러리 방문

Fei Fei Fang et al.
ACS applied materials & interfaces, 3(9), 3487-3495 (2011-08-06)
The dispersion stability of soft magnetic carbonyl iron (CI)-based magnetorheological (MR) fluids was improved by applying a unique functional coating composed of a conducting polyaniline layer and a multiwalled carbon nanotube nest to the surfaces of the CI particles via
Anders Bergh et al.
Carbohydrate research, 343(10-11), 1808-1813 (2008-05-13)
Cationic iron carbonyl cyclohexadiene complexes were employed in the derivatization of the 3-OH position of unprotected and protected methyl beta-D-galactopyranosides using two different approaches, giving access to galactopyranosides with an aromatic or cyclohexadienoic functionality in this position.
Kyoko Hibi et al.
Analytical and bioanalytical chemistry, 391(4), 1147-1152 (2008-04-29)
Bacterial cold water disease, caused by Flavobacterium psychrophilum, is a serious problem in the aquaculture industry worldwide. Several methods to prevent and treat cold water disease have been studied. Although detection at the early stage of F. psychrophilum infection is
John T Tsalavoutis et al.
Journal of computational chemistry, 31(10), 1969-1978 (2010-01-21)
The equilibrium structures and vibrational frequencies of the iron complexes [Fe(0)(CN)(n)(CO)(5-n)](n-) and [Fe(II)(CN)(n)(CO)(5-n)](2-n) (n = 0-5) have been calculated at the BP86 level of theory. The Fe(0) complexes adopt trigonal bipyramidal structures with the cyano ligands occupying the axial positions
Pro-oxidants or anti-oxidant defenses? Which one to blame in non-alcoholic steatohepatitis pathogenesis?
Isabelle A Leclercq
Journal of gastroenterology and hepatology, 27(11), 1651-1653 (2012-10-31)

문서

Solvothermal synthesis of nanoparticles: applications from nanocircuits and nano-optical circuits to nanomagnetics and biotech.

Magnetic nanoparticles have attracted tremendous attention due to their novel properties and their potential applications in magnetic recording, magnetic energy storage and biomedicine.

Spintronics offer breakthroughs over conventional memory/logic devices with lower power, leakage, saturation, and complexity.

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

질문

1–2 / 2 질문  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 답변
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 답변
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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