1.13364

テトラヒドロフラン-d₈

deuteration degree min 99.5% for NMR spectroscopy MagniSolv^™

• 別名: オクタ重水素化テトラヒドロフラン, 重水素化テトラヒドロフラン
• 実験式（ヒル表記法）: C₄D₈O
• CAS番号: 1693-74-9
• 分子量: 80.16
• Beilstein: 111854
• MDL番号: MFCD00044238
• UNSPSCコード: 12142201
• EC Index Number: 216-898-4
• NACRES: NA.22

特性

• 品質水準: 200
• 形状: liquid
• 自己発火温度: 215 °C
• 有効性: 1650 mg/kg LD₅₀, oral (Rat)
• テクニック: NMR: suitable
• 不純物: ≤0.030% Water (H<SUB>2</SUB>O) (NMR); ≤0.050% Water (H<SUB>2</SUB>O) (Karl Fischer)
• 屈折率: n20/D 1.403 (lit.)
• bp: 65-66 °C (lit.)
• mp: −106 °C (lit.)
• 転移温度: flash point -17.5 °C
• 密度: 0.985 g/mL at 25 °C (lit.)
• 質量シフト: M+8
• 保管温度: 2-8°C
• SMILES記法: [2H]C1([2H])OC([2H])([2H])C([2H])([2H])C1([2H])[2H]
• InChI: 1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2
• InChI Key: WYURNTSHIVDZCO-SVYQBANQSA-N

詳細

詳細

A wide range of MagniSolv deuterated solvents with extremely low residual water, excellent chemical purity, and the highest isotopic enrichment available can satisfy the most demanding requirements of researchers. Depending on application and sensitivity of the NMR spectrometer our offer solvents with deuteration degrees between 98% and 99.96%. In case of all the water soluble deuterated standard products, water content is specified according to both Karl Fischer and NMR.

アプリケーション

• Experimental and Theoretical Study of CO2 Insertion into Ruthenium Hydride Complexes.: This research provides insights into the mechanistic pathways for CO2 reactivity with ruthenium hydride complexes, potentially relevant for catalytic applications including transformations involving Tetrahydrofuran-d₈ (Ramakrishnan et al., 2016).



• Syntheses, structures, and NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds.: Details the synthesis and structural characterization of trimethyltin compounds, useful for understanding the coordination chemistry that may involve Tetrahydrofuran-d₈ as a solvent or structural analogue (Lichtscheidl et al., 2015).



• NMR studies of coupled low- and high-barrier hydrogen bonds in pyridoxal-5′-phosphate model systems in polar solution.: Discusses the application of NMR spectroscopy in studying hydrogen bonding interactions, where Tetrahydrofuran-d₈ could be utilized as a deuterated solvent for enhanced spectral clarity (Sharif et al., 2007).



• Stable hydrocarbon diradical, an analogue of trimethylenemethane.: Investigates stable hydrocarbon diradicals, where Tetrahydrofuran-d₈ may be used as part of the experimental setup to stabilize reactive intermediates or as a solvent to study radical stability (Rajca et al., 2005).

アナリシスノート

Deuteration degree: ≥ 99.50 %
Water (NMR, H₂O): ≤ 0.030 %
Performance test (NMR-spectrum): passes test
Water (K. Fischer, H₂O + D₂O): ≤ 0.050 %

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法的情報

MAGNISOLV is a trademark of Merck KGaA, Darmstadt, Germany

安全性情報

• ピクトグラム: GHS02,GHS07,GHS08
• シグナルワード: Danger
• 危険有害性情報: H225 - H302 - H319 - H335 - H336 - H351
• 注意書き: P202 - P210 - P233 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• 危険有害性の分類: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2
• 補足的ハザード: EUH019
• 保管分類コード: 3 - Flammable liquids
• WGK: WGK 1
• 引火点(°F): 1.4 °F - closed cup
• 引火点(℃): -17 °C - closed cup