900715

N-((S)-1-((4S,5S)-4-Benzyl-5-phenyl-4,5-dihydrooxazol-2-yl)-2,2-dimethylpropyl)acetamide

• 別名: Chiral MPAO ligand
• 実験式（ヒル表記法）: C₂₃H₂₈N₂O₂
• CAS番号: 2079094-32-7
• 分子量: 364.48
• UNSPSCコード: 12161600
• NACRES: NA.22

特性

• アッセイ: ≥95%
• フォーム: powder or crystals
• 反応適合性: reaction type: C-C Bond Formation; reagent type: catalyst; reagent type: ligand; reaction type: C-H Activation
• mp: 130 °C
• 官能基: amide; phenyl
• 保管温度: 2-8°C

詳細

アプリケーション

N-((S)-1-((4S,5S)-4-Benzyl-5-phenyl-4,5-dihydrooxazol-2-yl)-2,2-dimethylpropyl)acetamide is a chiral ligand developed by Jin-Quan Yu′s lab for Pd(II)-catalyzed enantioselective β-C(sp³)H arylation, alkenylation, and alkynylation. This mono-protected aminomethyl oxazoline (MPAO) ligand was used in the challenging desymmetrization of isopropyl groups.

その他情報

Formation of α-chiral centers by asymmetric β-C(sp³)–H arylation, alkenylation, and alkynylation

安全性情報

• 危険有害性情報: H413
• 危険有害性の分類: Aquatic Chronic 4
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable