731110

ジ-n-ブチルマグネシウム 溶液

1 M in ether and hexanes

• 化学式: [CH₃(CH₂)₃]₂Mg
• CAS番号: 1191-47-5
• 分子量: 138.53
• Beilstein: 3535184
• MDL番号: MFCD00015225
• UNSPSCコード: 26111700
• PubChem Substance ID: 329764622
• NACRES: NA.23

特性

• フォーム: solution
• 環境により配慮した代替製品の特徴: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 濃度: 1 M in ether and hexanes
• 密度: 0.736 g/mL at 25 °C
• 環境により配慮した代替製品カテゴリ: Enabling,
• SMILES記法: CCCC[Mg]CCCC
• InChI: 1S/2C4H9.Mg/c2*1-3-4-2;/h2*1,3-4H2,2H3;
• InChI Key: ODHFJIDDBSDWNU-UHFFFAOYSA-N

詳細

詳細

Di-n-butylmagnesium solution may be prepared by hydrogenation of magnesium, followed by reacting it with 1-butene.[1]

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アプリケーション

Electrochemically inactive [Mg₂(μ-Cl)₃•6THF][C₂H₅AlCl₃] crystal may be obtained from an electrolyte composed of Di-n-butylmagnesium and ethylaluminum dichloride.[2] Di-n-butylmagnesium may be used in the carbon metallation of α-olefins.[3] A study reports the possible use of the organometallic compound in the intercalation of magnesium and zinc into the layers of TiS₂ or WO₂Cl₂.[4] Interaction of lithium alkoxide with di-n-butylmagnesium was investigated.[5]

安全性情報

• ピクトグラム: GHS02,GHS08,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H224,H250,H260,H302,H304,H314,H336,H361f,H412
• 注意書き: P210 - P231 + P232 - P233 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378 - P403 + P233
• 危険有害性の分類: Acute Tox. 4 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 1 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• ターゲットの組織: Central nervous system
• 補足的ハザード: EUH014,EUH019
• 保管分類コード: 4.2 - Pyrophoric and self-heating hazardous materials
• WGK: WGK 3
• 引火点(°F): -22.0 °F
• 引火点(℃): -30 °C