62562

リチウムメトキシド 溶液

~10% in methanol (T, ~2.2 M)

• 別名: リチウムメチラート
• 化学式: CH₃OLi
• CAS番号: 865-34-9
• 分子量: 37.97
• Beilstein: 3552389
• MDL番号: MFCD00036357
• UNSPSCコード: 12352300
• PubChem Substance ID: 57651898
• NACRES: NA.22

特性

• 濃度: ~10% in methanol (T, ~2.2 M)
• 密度: 0.85 g/mL at 20 °C
• SMILES記法: [Li+].C[O-]
• InChI: 1S/CH3O.Li/c1-2;/h1H3;/q-1;+1
• InChI Key: JILPJDVXYVTZDQ-UHFFFAOYSA-N

詳細

詳細

Lithium methoxide solution is a useful reagent in organic synthesis with a range of applications. For example, it is used as a strong base in deprotonation reactions of various acidic functional groups, such as alcohols, phenols, and carboxylic acids. It also acts as a catalyst in esterification reactions. It can catalyze the reaction of carboxylic acids with alcohols to form esters.

アプリケーション

Lithium methoxide solution (10% in methanol) can be used as a source of lithium ions in the synthesis of dilithium (2,3-dilithium-oxy)-terephthalate, which is studied for its electrochemical behavior.

安全性情報

• ピクトグラム: GHS02,GHS06,GHS08,GHS05
• シグナルワード: Danger
• 危険有害性情報: H225,H251,H301 + H311 + H331,H314,H370
• 注意書き: P210 - P235 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B - STOT SE 1
• ターゲットの組織: Eyes,Central nervous system
• 補足的ハザード: EUH014
• 保管分類コード: 4.2 - Pyrophoric and self-heating hazardous materials
• WGK: WGK 2
• 引火点(°F): 53.6 °F
• 引火点(℃): 12 °C
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter