445274

Imino-tris(dimethylamino)phosphorane

97%

• 別名: N,N,N′,N′,N″,N″-Hexamethylphosphorimidic triamide, Phosphazene base P₁-H
• 化学式: [(CH₃)₂N]₃P=NH
• CAS番号: 49778-01-0
• 分子量: 178.22
• Beilstein: 1933051
• MDL番号: MFCD00216725
• UNSPSCコード: 12161700
• PubChem Substance ID: 24868170
• NACRES: NA.22

特性

• 品質水準: 200
• アッセイ: 97%
• フォーム: liquid
• 屈折率: n20/D 1.476 (lit.)
• 密度: 0.979 g/mL at 25 °C (lit.)
• 官能基: amine
• SMILES記法: CN(C)P(=N)(N(C)C)N(C)C
• InChI: 1S/C6H19N4P/c1-8(2)11(7,9(3)4)10(5)6/h7H,1-6H3
• InChI Key: GKTNLYAAZKKMTQ-UHFFFAOYSA-N

詳細

アプリケーション

Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen–Bases

Imino-tris(dimethylamino)phosphorane is a base that can be used:

• As a reagent in the deboronation of ortho and meta carboranes.[1]
• As an organocatalyst in the synthesis of cyclic organic carbonates using glycerol under solvent-free conditions.[2]

安全性情報

• ピクトグラム: GHS05
• シグナルワード: Danger
• 危険有害性情報: H314
• 注意書き: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• 危険有害性の分類: Eye Dam. 1 - Skin Corr. 1B
• 保管分類コード: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• 引火点(°F): 235.4 °F - closed cup
• 引火点(℃): 113 °C - closed cup
• 個人用保護具 (PPE): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter