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251755

Sigma-Aldrich

Osmium tetroxide solution

4 wt. % in H2O

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2 ML
153,00 €
5 ML
259,00 €
10 ML
529,00 €

153,00 €


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2 ML
153,00 €
5 ML
259,00 €
10 ML
529,00 €

About This Item

Formula condensata:
OsO4
Numero CAS:
Peso molecolare:
254.23
Numero MDL:
Codice UNSPSC:
12352303
ID PubChem:
NACRES:
NA.21

153,00 €


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Tensione di vapore

1.23 psi ( 20 °C)
3.55 psi ( 55 °C)

Livello qualitativo

Stato

liquid

Impiego in reazioni chimiche

reagent type: oxidant

Concentrazione

3.5-4.5% (OsO4)
4 wt. % in H2O

Densità

1.0 g/mL at 20 °C
1.04 g/mL at 25 °C

Temperatura di conservazione

2-8°C

Stringa SMILE

O=[Os](=O)(=O)=O

InChI

1S/4O.Os
VUVGYHUDAICLFK-UHFFFAOYSA-N

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Descrizione generale

OsO4 (4wt% in H2O) is widely employed in organic synthesis especially for hydroxylation reactions. Additionally, it is also involved in the oxidative cleavage of alkenes.

Applicazioni


  • In situ X-ray-assisted electron microscopy staining for large biological samples.: This study explores the use of osmium tetroxide solution for X-ray-assisted electron microscopy staining, enhancing the visualization of large biological samples (Ströh et al., 2022).

  • Application of the electron microscope to the cytochemical peroxidase reaction in salamander leukocytes.: The use of osmium tetroxide solution in electron microscopy enhances the cytochemical analysis of peroxidase reactions in salamander leukocytes, providing clear and detailed images (MITSUI, 1960).


Pittogrammi

Skull and crossbonesCorrosion

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 2 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2

Codice della classe di stoccaggio

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


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Certificati d'analisi (COA)

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Asymmetric induction in the reaction of osmium tetroxide with olefins.
Hentges SG and Barry Sharpless K.
Journal of the American Chemical Society, 102(12), 4263-4265 (1980)
On stereochemistry of osmium tetroxide oxidation of allylic alcohol systems: empirical rule.
Cha JK, et al.
Tetrahedron Letters, 24(37), 3943-3946 (1983)
Kinetics of Oxidation of Some Fluoroquinolones by Hexacyanoferrate (III) in Alkaline Medium.
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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