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C31104

Sigma-Aldrich

3-Chloro-2-chloromethyl-1-propene

99%

Sinonimo/i:

1,1-Bis(chloromethyl)ethylene, Methallyl dichloride

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161,00 €
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413,00 €

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10 G
161,00 €
50 G
413,00 €

About This Item

Formula condensata:
CH2=C(CH2Cl)2
Numero CAS:
Peso molecolare:
125.00
Beilstein:
1560178
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

161,00 €


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Densità del vapore

3.12 (vs air)

Livello qualitativo

Saggio

99%

Stato

liquid

Temp. autoaccensione

896 °F

Limite di esplosione

8.1 %

Indice di rifrazione

n20/D 1.4753 (lit.)

P. ebollizione

138 °C (lit.)

Punto di fusione

−14 °C (lit.)

Densità

1.08 g/mL at 25 °C (lit.)

Temperatura di conservazione

2-8°C

Stringa SMILE

ClCC(=C)CCl

InChI

1S/C4H6Cl2/c1-4(2-5)3-6/h1-3H2
XJFZOSUFGSANIF-UHFFFAOYSA-N

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Applicazioni

3-Chloro-2-chloromethyl-1-propene can be used in the synthesis of 2,11-bis(methylidene)spermine, an inhibitor of spermine oxidase[1] and branched side chains of conjugated polymers.[2][3] It can also be used in the intermolecular [2+2] photocycloaddition during the total synthesis of (−)-grandisol.[4]

Pittogrammi

FlameSkull and crossbones

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

96.8 °F

Punto d’infiammabilità (°C)

36 °C

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificati d'analisi (COA)

Lot/Batch Number

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Enantioselective Intermolecular [2+ 2] Photocycloaddition Reaction of Cyclic Enones and Its Application in a Synthesis of (−)-Grandisol.
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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