633089

trans-N,N′-Dimethylcyclohexane-1,2-diamine

97%

• Sinonimo/i: N,N′-Dimethyl-trans-1,2-cyclohexanediamine, rel-(1R,2R)-N1,N2-Dimethyl-1,2-cyclohexanediamine, trans-1,2-Bis(methylamino)cyclohexane, trans-N,N′-Dimethyl-1,2-cyclohexanediamine, trans-N,N′-Dimethyl-1,2-diaminocyclohexane
• Formula empirica (notazione di Hill): C₈H₁₈N₂
• Numero CAS: 67579-81-1
• Peso molecolare: 142.24
• Numero MDL: MFCD03001702
• Codice UNSPSC: 12352100
• ID PubChem: 24882536
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Saggio: 97%
• Indice di rifrazione: n20/D 1.472 (lit.)
• P. eboll.: 78-80 °C/18 mmHg (lit.)
• Densità: 0.902 g/mL at 25 °C (lit.)
• Stringa SMILE: CN[C@@H]1CCCC[C@H]1NC
• InChI: 1S/C8H18N2/c1-9-7-5-3-4-6-8(7)10-2/h7-10H,3-6H2,1-2H3/t7-,8-/m1/s1; JRHPOFJADXHYBR-HTQZYQBOSA-N

Descrizione

Descrizione generale

trans-N,N′-Dimethylcyclohexane-1,2-diamine is a ligand used to promote N-alkenylation and N-alkylation reactions of amides.

Applicazioni

trans-N,N′-dimethylcyclohexane-1,2-diamine can be used as a ligand in the synthesis of the following products via copper catalyzed C-N coupling reactions:

• vinylsulfoximines obtained from NH sulfoximes and vinyl bromides
• N-arylpyridones obtained via reaction between 2-substituted pyridines and aryl halides
• N-aryl amines obtained via reaction between amines and aryl iodides/aryl bromides

Informazioni sulla sicurezza

• Pittogrammi: GHS05,GHS07
• Avvertenze: Danger
• Indicazioni di pericolo: H302,H314
• Consigli di prudenza: P270 - P280 - P301 + P312 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
• Classi di pericolo: Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
• Codice della classe di stoccaggio: 8A - Combustible corrosive hazardous materials
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Dispositivi di protezione individuale: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter