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Sigma-Aldrich

Iron(0) pentacarbonyl

greener alternative

>99.99% trace metals basis

Sinonimo/i:

Iron(0) carbonyl, Pentacarbonyliron(0)

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About This Item

Formula condensata:
Fe(CO)5
Numero CAS:
13463-40-6
Peso molecolare:
195.90
Numero CE:
236-670-8
Numero MDL:
MFCD00011001
Codice UNSPSC:
12352103
ID PubChem:
24871777
NACRES:
NA.23

Densità del vapore

6.74 (vs air)

Tensione di vapore

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

Saggio

>99.99% trace metals basis

Forma fisica

liquid

Temp. autoaccensione

122 °F

Impiego in reazioni chimiche

core: iron
reagent type: catalyst

Caratteristiche più verdi

Catalysis
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sustainability

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Indice di rifrazione

n20/D 1.5196 (lit.)

P. eboll.

103 °C (lit.)

Punto di fusione

−20 °C (lit.)

Densità

1.49 g/mL at 25 °C (lit.)

Categoria alternativa più verde

, Aligned

Temperatura di conservazione

2-8°C

Stringa SMILE

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.Fe/c5*1-2;
FYOFOKCECDGJBF-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Iron(0) pentacarbonyl is a straw-yellow to brilliant orange liquid soluble in organic solvents. It is widely used as a precursor for synthesizing iron oxide nanoparticles, which have applications in the field of energy conversion and storage due to their catalytic properties and ability to enhance electron transport.
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Applicazioni

Chemical Synthesis of Monodisperse Magnetic Nanoparticles
Iron(0) pentacarbonyl can be used:
  • To fabricate Fe-based anode materials for high-performance aqueous secondary Ni−Fe batteries. It helps to achieve good safety, high power density, long term-life cycle, and high energy density.
  • As a precursor to synthesize highly stable, colloidal magnetic iron nanoparticles with narrow size distribution. These nanoparticles are potential candidates for MRI contrasting agents and magnetically separable catalysts.
  • To synthesize zero valent sustainable iron nanocatalysts for reduction reactions.

Reactant for:
  • Addition reactions
  • Decomposition via photolysis
  • Preparation of magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution via thermal decomposition
  • Preparation of a heptanuclear iron carbonyl cluster used in catalytic hydrosilane reduction of carboxamides

  • Precursor for preparation of Fe nanoparticles for photocatalytic hydrogen evolution under highly basic conditions

Pittogrammi

FlameSkull and crossbones
GHS02,GHS06

Avvertenze

Danger

Indicazioni di pericolo

H225,H300 + H330,H311

Classi di pericolo

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

5.0 °F - closed cup

Punto d’infiammabilità (°C)

-15 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificati d'analisi (COA)

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The journal of physical chemistry. B, 116(40), 12341-12348 (2012-09-15)
A new class of magnetoelastic gel that demonstrates drastic and reversible changes in storage modulus without using strong magnetic fields was obtained. The magnetic gel consists of carrageenan and carbonyl iron particles. The magnetic gel with a volume fraction of
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Analytical and bioanalytical chemistry, 391(4), 1147-1152 (2008-04-29)
Bacterial cold water disease, caused by Flavobacterium psychrophilum, is a serious problem in the aquaculture industry worldwide. Several methods to prevent and treat cold water disease have been studied. Although detection at the early stage of F. psychrophilum infection is
Fei Fei Fang et al.
ACS applied materials & interfaces, 3(9), 3487-3495 (2011-08-06)
The dispersion stability of soft magnetic carbonyl iron (CI)-based magnetorheological (MR) fluids was improved by applying a unique functional coating composed of a conducting polyaniline layer and a multiwalled carbon nanotube nest to the surfaces of the CI particles via
Li Long et al.
Dalton transactions (Cambridge, England : 2003), 41(31), 9482-9492 (2012-07-04)
Reaction of Fe(3)(CO)(12) with pyridinyl thioester ligand PyCH(2)SCOCH(3) (L(1), Py = pyridin-2-yl) produced complex, [Fe(2)(κ-COCH(3))(μ-SCH(2)Py)(CO)(5)] (1) (PyCH(2)S = pyridin-2-ylmethanethiolate). When complex 1 reacted with PPh(3), a monosubstituted complex, [Fe(2)(κ-COCH(3))(μ-SCH(2)Py)(CO)(4)PPh(3)] (2), was derived. Reaction of the same precursor with analogous thioester
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