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246050

Sigma-Aldrich

1,5-Cyclooctadiene

purified by redistillation, ≥99%

Sinonimo/i:

1,5-COD, cis-1,5-Cyclooctadiene, COD

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100 ML
58,50 €
800 ML
287,00 €

58,50 €

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100 ML
58,50 €
800 ML
287,00 €

About This Item

Formula empirica (notazione di Hill):
C8H12
Numero CAS:
111-78-4
Peso molecolare:
108.18
Beilstein:
2036542
Numero CE:
203-907-1
Numero MDL:
MFCD00001752
Codice UNSPSC:
12352100
ID PubChem:
24854773
NACRES:
NA.22

58,50 €

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Tensione di vapore

25.8 mmHg ( 37.7 °C)
6.8 mmHg ( 25 °C)

Livello qualitativo

100

Saggio

≥99%

Stato

liquid

Temp. autoaccensione

431 °F

Purificato mediante

redistillation

non contiene

stabilizer

Indice di rifrazione

n20/D 1.493 (lit.)

P. ebollizione

149-150 °C (lit.)

Punto di fusione

−69 °C (lit.)

Densità

0.882 g/mL at 25 °C (lit.)

Stringa SMILE

C1CC=CCCC=C1

InChI

1S/C8H12/c1-2-4-6-8-7-5-3-1/h1-2,7-8H,3-6H2/b2-1-,8-7-
VYXHVRARDIDEHS-QGTKBVGQSA-N

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Categorie correlate

Applicazioni

1,5-Cyclooctadiene was used as a catalyst in the synthesis of aminoindene derivatives by the [3+2] annulation of ketimines with internal and terminal alkynes[1].

Avvertenze

Danger

Indicazioni di pericolo

H226,H302 + H332,H304,H410

Classi di pericolo

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

100.4 °F - closed cup

Punto d’infiammabilità (°C)

38 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
SHBR9071
SHBL6313
SHBJ2003
SHBF9503V
SHBG0583V

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Midori Nagamoto et al.
Chemical communications (Cambridge, England), 50(47), 6274-6277 (2014-05-07)
[3 + 2] Annulation of ketimines with internal and terminal alkynes proceeded via C-H activation to give aminoindene derivatives in high yields, which is catalyzed by a cationic iridium complex coordinated with 1,5-cyclooctadiene (cod).
Eleonora Cavallari et al.
The journal of physical chemistry. B, 119(31), 10035-10041 (2015-07-15)
Hyperpolarization of (13)C carboxylate signals of metabolically relevant molecules, such as acetate and pyruvate, was recently obtained by means of ParaHydrogen Induced Polarization by Side Arm Hydrogenation (PHIP-SAH). This method relies on functionalization of the carboxylic acid with an unsaturated
Adrian Tlahuext-Aca et al.
Dalton transactions (Cambridge, England : 2003), 43(42), 15997-16005 (2014-09-19)
Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while maintaining good selectivity and atom economy. The catalytic system shows low to moderate tolerance for fluoro-, trifluoromethyl-

Domande

1–2 di 2 domande  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Utile?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Utile?

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