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Documenti

130079

Sigma-Aldrich

Methyltriphenylphosphonium bromide

98%

Sinonimo/i:

TPMP, Triphenylmethylphosphonium bromide, triphenylmethylphosphonium bromide

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About This Item

Formula condensata:
CH3P(C6H5)3Br
Numero CAS:
1779-49-3
Peso molecolare:
357.22
Beilstein:
3599467
Numero CE:
217-218-9
Numero MDL:
MFCD00011804
Codice UNSPSC:
12352002
ID PubChem:
24847941
NACRES:
NA.22

Saggio

98%

Forma fisica

powder

Impiego in reazioni chimiche

reaction type: C-C Bond Formation

Punto di fusione

230-234 °C (lit.)

Stringa SMILE

[Br-].C[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C19H18P.BrH/c1-20(17-11-5-2-6-12-17,18-13-7-3-8-14-18)19-15-9-4-10-16-19;/h2-16H,1H3;1H/q+1;/p-1
LSEFCHWGJNHZNT-UHFFFAOYSA-M

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Categorie correlate

Applicazioni

Used widely for methylenation via the Wittig reaction
Wittig olefination salt employed recently in a synthesis of an enyne which, via ring closing metathesis, provided a benzazepine ring system.

Pittogrammi

Skull and crossbonesEnvironment
GHS06,GHS09

Avvertenze

Danger

Indicazioni di pericolo

H301,H411

Consigli di prudenza

P273 - P301 + P310 + P330

Classi di pericolo

Acute Tox. 3 Oral - Aquatic Chronic 2

Codice della classe di stoccaggio

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

>464.0 °F

Punto d’infiammabilità (°C)

> 240 °C

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

Certificati d'analisi (COA)

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Sigma-Aldrich

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Sigma-Aldrich

412252

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Synlett, 2771-2771 (2006)
Fengling Cui et al.
Journal of pharmaceutical and biomedical analysis, 43(3), 1033-1038 (2006-12-23)
A method for the determination of bismuth in pharmaceutical products using methyltriphenylphosphonium bromide as a molecular probe based on the resonance light scattering (RLS) technique was developed. In the presence of Tween-20, bismuth reacts with a large excess of I(-)
Brian D Fink et al.
The Journal of pharmacology and experimental therapeutics, 342(3), 709-719 (2012-06-05)
Mitochondrial-targeted analogs of coenzyme Q (CoQ) are under development to reduce oxidative damage induced by a variety of disease states. However, there is a need to understand the bioenergetic effects of these agents and whether or not these effects are
Abhijit Mukhopadhyay et al.
Advanced drug delivery reviews, 59(8), 729-738 (2007-07-31)
Mitochondria is where the bulk of the cell's ATP is produced. Mutations occur to genes coding for members of the complexes involved in energy production. Some are a result of damages to nuclear coded genes and others to mitochondrial coded
D P Nolan et al.
European journal of biochemistry, 267(15), 4615-4623 (2000-07-21)
The plasma-membrane potential (Delta(psi)p) in bloodstream forms of Trypanosoma brucei was studied using several different radiolabelled probes: 86Rb+ and [14C]SCN- were used to report Delta(psi)p directly because they distribute in easily measured quantities across the plasma membrane only, and [3H]methyltriphenylphosphonium
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