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100242

Sigma-Aldrich

3-Aminophenol

98%

Sinonimo/i:

m-Aminophenol

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5 G
26,00 €
100 G
45,70 €
500 G
99,50 €

About This Item

Formula condensata:
H2NC6H4OH
Numero CAS:
591-27-5
Peso molecolare:
109.13
Beilstein:
636059
Numero CE:
209-711-2
Numero MDL:
MFCD00007786
Codice UNSPSC:
12352100
ID PubChem:
24846518
NACRES:
NA.22

26,00 €

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Livello qualitativo

200

Saggio

98%

Stato

solid

P. ebollizione

164 °C/11 mmHg (lit.)

Punto di fusione

120-124 °C (lit.)

Stringa SMILE

Nc1cccc(O)c1

InChI

1S/C6H7NO/c7-5-2-1-3-6(8)4-5/h1-4,8H,7H2
CWLKGDAVCFYWJK-UHFFFAOYSA-N

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Applicazioni

3-Aminophenol has been used in the synthesis of disulfonated bis[4-(3-aminophenoxy)phenyl]sulfone (S-BAPS).[1]
It can be used to synthesize:
  • Methyl 2-oxo-7-[(triphenylphosphoranylidene)amino]-2H-chromene-4-carboxylate by reacting with dimethyl acetylenedicarboxylate (DMAD) in the presence of triphenylphosphine.[2]
  • 3-Amino-2-cyclohexen-1-one via palladium-catalyzed hydrogenation.[3]

Pittogrammi

Exclamation markEnvironment
GHS07,GHS09

Avvertenze

Warning

Indicazioni di pericolo

H302 + H332,H319,H411

Classi di pericolo

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 2

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

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Certificati d'analisi (COA)

Lot/Batch Number
MKCP8632
0000231869
MKCT0738
STBK0386
STBJ1605

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SAFC

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Sigma-Aldrich

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Sijing Chen et al.
Polymers, 11(6) (2019-06-20)
Benzoxazine containing fluorinated aromatic ether nitrile linkage (FAEN-Bz) had been synthesized from 2,6-dichlorobenzonitrile, 4,4'-(hexafluoroisopropylidene)diphenol (bisphenol AF), 3-Aminophenol, formaldehyde, phenol by condensation polymerization and Mannich ring-forming reaction. Structures of the monomer were verified by Proton NMR spectrum (1H-NMR) and Fourier transform
A Practical and One-Pot Procedure for the Synthesis of 3-Amino-2-cyclohexen-1-one from 3-Aminophenol.
Sajiki H
Organic Process Research & Development, 9(2), 219-220 (2005)
Vinyltriphenylphosphonium salt mediated synthesis of 1, 4-benzoxazine and coumarin derivatives.
Yavari I, et al.
Tetrahedron, 58(34), 6895-6899 (2002)
Ping-Chih Hsu et al.
Oncology reports, 42(2), 697-707 (2019-06-25)
Human non‑small cell lung cancer (NSCLC) is associated with an extremely poor prognosis especially for the 40% of patients who develop brain metastasis, and few treatment strategies exist. Cucurbitacin E (CuE), an oxygenated tetracyclic triterpenoid isolated from plants particularly of
Woon Yong Sohn et al.
Physical chemistry chemical physics : PCCP, 13(15), 7037-7042 (2011-03-15)
3-Aminophenol (3AP) has two conformers, cis and trans, depending on the orientation of the OH group relative to the NH(2) group. While both conformers are found in the jet-cooled spectra of 3AP, only the trans isomer was found in the
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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