937118

QPhos Pd G3 ChemBeads

• Szinonimák: QPhos G3 Palladacycle ChemBeads, QPhos Palladacycle ChemBeads, [2′-(Amino-κN)[1,1′-biphenyl]-2-yl-κC][1′-[bis(1,1-dimethylethyl)phosphino]-1,2,3,4,5-pentaphenylferrocene](methanesulfonato-κO)palladium ChemBeads
• Tapasztalati képlet (Hill-képlet): C₆₁H₆₀FeNO₃PPdS
• CAS-szám: 2021255-91-2
• Molekulatömeg: 1080.44
• MDL-szám: MFCD32215369
• UNSPSC kód: 12352100

Tulajdonságok

• Forma: solid
• Minőségi szint: 100
• összetétel: , 4-6 wt. % (loading)
• reakcióalkalmasság: reagent type: catalyst
• SMILES string: O=S(=O)([O-][Pd+2]1([C-]=2C=CC=CC2C=3C=CC=CC3[NH2]1)[P](C(C)(C)C)(C(C)(C)C)[C-]45[CH]6=[CH]7[CH]8=[CH]4[Fe+2]7869%10%11%125C=%13(C=%14C=CC=CC%14)C%12(C=%15C=CC=CC%15)=C%11(C=%16C=CC=CC%16)[C-]%10(C=%17C=CC=CC%17)C%139C=%18C=CC=CC%18)C
• InChI: InChI=1S/C35H25.C13H22P.C12H10N.CH4O3S.Fe.Pd/c1-6-16-26(17-7-1)31-32(27-18-8-2-9-19-27)34(29-22-12-4-13-23-29)35(30-24-14-5-15-25-30)33(31)28-20-10-3-11-21-28;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;;/h1-25H;7-10H,1-6H3;1-6,8-9H,13H2;1H3,(H,2,3,4);;/q3*-1;;2*+2/p-1
• Nemzetközi kémiai azonosító kulcs: NNVAEYGNFLUPRU-UHFFFAOYSA-M

Leírás

Általános leírás

The ChemBeads product of the QPhos ligand combined with the Buchwald third Generation Palladacycle. Loaded at 5% wt. on glass beads for use in high-throughput expermentation (HTE). QPhos Pd G3 has been used in:

• The synthesis of complex druglike moleucle via Negisihi couplings using a high-throughput experimentation approach.[1]
• The regioselective arylboration of isoprene using cooperative Pd/Cu catalysis.[2]
• The total synthesis of Phainanoid A and its synthetic analogues.[3][4]

Alkalmazás

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

For general uses, product is also available in powdered form 903027

Tulajdonságok és előnyök

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Biztonsági adatok

• Tárolási osztály kódja: 11 - Combustible Solids
• WGK: WGK 3