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Merck
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文件

C4991

Sigma-Aldrich

头孢甘氨酸

≥97% (HPLC), solid

别名:

NSC 318735

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About This Item

经验公式（希尔记法）:
C45H53NO14
CAS号:
71610-00-9
分子量:
831.90
MDL號碼:
MFCD01075131
分類程式碼代碼:
12352200
PubChem物質ID:
24724441
NACRES:
NA.77

化驗

≥97% (HPLC)

形狀

solid

溶解度

DMSO: soluble 14 mg/mL

抗生素活性譜

neoplastics

作用方式

DNA synthesis | interferes

儲存溫度

room temp

SMILES 字串

C\C=C(/C)C(=O)N[C@H]([C@@H](O)C(=O)O[C@H]1C[C@@]2(O)[C@@H](OC(=O)c3ccccc3)C4[C@@](C)([C@@H](O)C[C@H]5OC[C@@]45OC(C)=O)C(=O)[C@H](OC(C)=O)C(=C1C)C2(C)C)c6ccccc6

InChI

1S/C45H53NO14/c1-9-23(2)39(52)46-33(27-16-12-10-13-17-27)34(50)41(54)58-29-21-45(55)38(59-40(53)28-18-14-11-15-19-28)36-43(8,30(49)20-31-44(36,22-56-31)60-26(5)48)37(51)35(57-25(4)47)32(24(29)3)42(45,6)7/h9-19,29-31,33-36,38,49-50,55H,20-22H2,1-8H3,(H,46,52)/b23-9+/t29-,30-,31+,33-,34+,35+,36?,38-,43+,44-,45+/m0/s1

InChI 密鑰

DBXFAPJCZABTDR-UJLUYDJNSA-N

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一般說明

化学结构:β-内酰胺

應用

头孢甘氨酸已被用于鉴定液体培养物中的真菌紫杉醇（抗癌药）。

生化／生理作用

头孢甘氨酸是从红豆杉中分离得到的，可用作抗真菌剂。
三尖杉宁碱是一种具有抗肿瘤、抗增殖特性的紫杉醇衍生物。

象形圖

CorrosionExclamation mark
GHS05,GHS07

訊號詞

Danger

危險聲明

H315,H318,H335

危險分類

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

分析证书(COA)

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紫杉醇 from semisynthetic, ≥98%

Sigma-Aldrich

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紫杉醇

K C Chan et al.
Journal of chromatography. B, Biomedical applications, 657(2), 301-306 (1994-07-15)
High-performance liquid chromatography (HPLC) and micellar electrokinetic chromatography (MEKC) were applied for the separation of taxol, cephalomannine, and baccatin III in crude extracts from the needle and bark of Taxus species. The chromatogram of the bark extract was cleaner than
Kannan Vivekanandan et al.
Rapid communications in mass spectrometry : RCM, 20(11), 1731-1735 (2006-05-06)
A strategy is developed for the identification of isocephalomannine in the presence of alkali metal ion adducts and other cephalomannine isomers in a paclitaxel active pharmaceutical ingredient. Intact molecular ion analyses and a sub-structural study have been performed for the
G Moyna et al.
Journal of chemical information and computer sciences, 36(6), 1224-1227 (1996-11-01)
A simple iterative method for superimposing sets of NMR derived structures and calculation of the root mean square deviation (RMSD) of the sets is described. It was compared to the commonly used algorithm involving pairwise best fitting in the conformational
Jiang-Wei Zhang et al.
Drug metabolism and disposition: the biological fate of chemicals, 36(2), 418-426 (2007-11-28)
To investigate how taxane's substituents at C3' affect its metabolism, we compared the metabolism of cephalomannine and paclitaxel, a pair of analogs that differ slightly at the C3' position. After cephalomannine was incubated with human liver microsomes in an NADPH-generating
Hongbo Wang et al.
Cancer letters, 268(1), 89-97 (2008-05-17)
Lx2-32c, a novel taxane derivative, is a semisynthetic analogue from cephalomannine. Its antitumor activity in vivo and in vitro was investigated in this study. Lx2-32c was cytotoxic (IC50=1.7+/-1.6nM) to various human tumor cell lines after 72h incubation. In vitro it
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