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Merck

675407

Sigma-Aldrich

丁基甲基醚

HPLC Plus, for HPLC, GC, and residue analysis, 99.9%

别名:

MTBE, 甲基叔丁基醚

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About This Item

线性分子式:
(CH3)3COCH3
CAS号:
分子量:
88.15
Beilstein:
1730942
EC號碼:
MDL號碼:
分類程式碼代碼:
12190000
PubChem物質ID:

等級

HPLC Plus
for residue analysis

品質等級

蒸汽密度

3.1 (vs air)

蒸汽壓力

4.05 psi

化驗

99.9%

形狀

liquid

自燃溫度

705 °F

expl. lim.

15.1 %

技術

HPLC: suitable
gas chromatography (GC): suitable

雜質

≤0.02% Water

蒸發殘留物

≤0.0001%

折射率

n20/D 1.369 (lit.)

bp

55-56 °C (lit.)

mp

-110 °C

密度

0.74 g/mL at 25 °C (lit.)

紫外吸收

λ: 210 nm Amax: ≤1.00
λ: 225 nm Amax: ≤0.50
λ: 250 nm Amax: ≤0.10
λ: 300 nm Amax: ≤0.005
λ: 400 nm Amax: ≤0.005

應用

food and beverages

SMILES 字串

COC(C)(C)C

InChI

1S/C5H12O/c1-5(2,3)6-4/h1-4H3

InChI 密鑰

BZLVMXJERCGZMT-UHFFFAOYSA-N

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一般說明

tert-Butyl methyl ether (MTBE) is a commonly used organic solvent. It can be synthesized by acid-catalyzed reaction between methanol and isobutene. It is an effective alternate to lead-containing additives for enhancing the octane rating of gasoline. The decomposition mechanism of MTBE by heat-assisted persulfate oxidation under different conditions has been reported. A study suggests that the addition of MTBE increases the number of active sites during polymerization of propene by the stopped-flow method.

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象形圖

FlameExclamation mark

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 2 - Skin Irrit. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

-18.4 °F - closed cup

閃點(°C)

-28 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves


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访问文档库

Lipid extraction by methyl-tert-butyl ether for high-throughput lipidomics.
Matyash V, et al.
Journal of Lipid Research, 49(5), 1137-1146 (2008)
Relative solubility, stability, and absorptivity of lutein and β-carotene in organic solvents.
Craft NE and Soares JH.
Journal of Agricultural and Food Chemistry, 40(3), 431-434 (1992)
New approach of catalyst-free biodiesel production from canola oil in supercritical tert-butyl methyl ether (MTBE).
Farobie O, et al.
Fuel: The Science and Technology of Fuel and Energy, 135, 172-181 (2014)
Eagleson M.
Concise Encyclopedia Chemistry, 154-154 (1994)
Role of tert-Butyl Methyl Ether (TBME) as an External Donor in Propene Polymerization with Dibutyl Phthalate (DBP)-Containing MgCl2-Supported Ti Catalysts Activated with Al(i-C4H9)3.
Ohnishi R and Konakazawa T.
Macromolecular Chemistry and Physics, 205(14), 1938-1947 (2004)

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