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Merck

31107-M

Sigma-Aldrich

氯化铵

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.5%

别名:

卤砂

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About This Item

线性分子式:
NH4Cl
CAS号:
分子量:
53.49
Beilstein:
4371014
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
eCl@ss:
38050207
PubChem物質ID:
NACRES:
NA.21

等級

ACS reagent
puriss. p.a.

品質等級

agency

USP/NF
reag. ISO
reag. Ph. Eur.

蒸汽密度

1.9 (vs air)

蒸汽壓力

1 mmHg ( 160.4 °C)

化驗

≥99.5%

形狀

crystalline powder

雜質

acidity or alkalinity, complies
bromides and iodides, complies
≤0.005% insoluble matter

pH值

4.5-5.5 (20 °C, 5%)

mp

340 °C (subl.) (lit.)

負離子痕跡

nitrate (NO3-): ≤5 mg/kg
phosphate (PO43-): ≤2 mg/kg
sulfate (SO42-): ≤20 mg/kg

正離子痕跡

As: ≤0.00005%
Ca: ≤0.0005%
Cu: ≤0.0002%
Fe: ≤0.0002%
K: ≤0.005%
Mg: ≤0.0005%
Na: ≤0.005%
Ni: ≤0.0001%
Pb: ≤0.0001%
Zn: ≤0.0002%
heavy metals: ≤5 mg/kg (by ICP-OES)

適合性

complies for appearance of solution

SMILES 字串

N.Cl

InChI

1S/ClH.H3N/h1H;1H3

InChI 密鑰

NLXLAEXVIDQMFP-UHFFFAOYSA-N

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應用

Ammonium chloride can be used as a catalyst:
  • To synthesize 3,4-dihydropyrimidin-2-(1H)-ones via solvent-free Biginelli condensation reaction.
  • For the aldol condensation of carbonyl compounds.
  • In the thia-Michael addition reaction of thiols to different α-enones.
It can also be used as:
  • A promoter in the enantioselective hydrogenation of an unprotected β-enamine amides.
  • A pH-adjuster in the preparation of waterborne glucose silicone resin.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Ammonium chloride-catalyzed one-pot synthesis of 3, 4-dihydropyrimidin-2-(1H)-ones under solvent-free conditions
Shaabani A, et al.
Tetrahedron Letters, 44, 857-859 (2003)
Ammonium chloride-catalyzed carbon-sulfur bond formation in water
Chen W, et al.
Catalysis Communications, 9, 1079-1081 (2008)
Physical and mechanical properties of poplar wood modified by glucose-urea-melamine resin/sodium silicate compound
Liu Q, et al.
Forests, 12, 127-127 (2021)
Identification of ammonium chloride as an effective promoter of the asymmetric hydrogenation of a beta-enamine amide
Clausen A, et al.
Organic Process Research & Development, 10, 723-726 (2006)
Neutron diffraction study of the crystal structure of ammonium chloride.
Levy, Henri A., and S. W. Peterson.
Physical Review, 86(5), 766-766 (1952)

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