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Merck
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文件

D79403

Sigma-Aldrich

环己基环己烷

99%

别名:

1,1′-双(环己基), BCH, 双环己烷

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About This Item

线性分子式:
C6H11C6H11
CAS号:
92-51-3
分子量:
166.30
Beilstein:
1848266
EC號碼:
202-161-4
MDL號碼:
MFCD00003815
分類程式碼代碼:
12352100
PubChem物質ID:
24894172
NACRES:
NA.22

化驗

99%

形狀

liquid

自燃溫度

473 °F

折射率

n20/D 1.478 (lit.)

bp

227 °C (lit.)

mp

3-4 °C (lit.)

密度

0.864 g/mL at 25 °C (lit.)

SMILES 字串

C1CCC(CC1)C2CCCCC2

InChI

1S/C12H22/c1-3-7-11(8-4-1)12-9-5-2-6-10-12/h11-12H,1-10H2

InChI 密鑰

WVIIMZNLDWSIRH-UHFFFAOYSA-N

基因資訊

human ... CYP1A2(1544) , ESR1(2099)

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相关类别

應用

联环己烷可用作反应剂，用于：      
  • 以亲核NaN3为叠氮源，通过Mn催化的氧化叠氮化反应合成1-叠氮-1,1′-联环己烷。      
  • 使用氟元素制备1-氟-1,1′-联环己烷。   
  • 在脂肪族Friedel-Crafts反应中，与三氯化铝和乙酰氯经C-H活化作用制备基于新型联环己烷的含氧分子砌块。

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Asp. Tox. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

197.6 °F - closed cup

閃點（°C）

92 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Linbin Niu et al.
Journal of the American Chemical Society, 142(41), 17693-17702 (2020-09-18)
The selective installation of azide groups into C(sp3)-H bonds is a priority research topic in organic synthesis, particularly in pharmaceutical discovery and late-stage diversification. Herein, we demonstrate a generalized manganese-catalyzed oxidative azidation methodology of C(sp3)-H bonds using nucleophilic NaN3 as
Lionel W Spack et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 34(6), 1052-1071 (2017-03-28)
The contamination of food by mineral oil hydrocarbons (MOHs) found in packaging is a long-running concern. A main source of MOHs in foods is the migration of mineral oil from recycled board into the packed food products. Consequently, the majority
Catherine L Lyall et al.
Organic & biomolecular chemistry, 11(9), 1468-1475 (2012-12-25)
The functionalisation of decalin by means of an "aliphatic Friedel-Crafts" reaction was reported over fifty years ago by Baddeley et al. This protocol is of current relevance in the context of C-H activation and here we demonstrate its applicability to
Brian D Fitz et al.
Journal of chromatography. A, 1392, 82-90 (2015-03-31)
Low thermal mass gas chromatography (LTM-GC) was evaluated for rapid, high peak capacity separations with three injection methods: liquid, headspace solid phase micro-extraction (HS-SPME), and direct vapor. An Agilent LTM equipped with a short microbore capillary column was operated at

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