所有图片(1)
About This Item
线性分子式:
C6H5CCH
CAS号:
分子量:
102.13
Beilstein:
605461
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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蒸汽压
17.6 mmHg ( 37.7 °C)
质量水平
方案
98%
杂质
<1% 1,4-dioxane
折射率
n20/D 1.549 (lit.)
沸点
142-144 °C (lit.)
溶解性
H2O: insoluble
alcohol: miscible
diethyl ether: miscible
密度
0.93 g/mL at 25 °C (lit.)
官能团
phenyl
储存温度
2-8°C
SMILES字符串
C#Cc1ccccc1
InChI
1S/C8H6/c1-2-8-6-4-3-5-7-8/h1,3-7H
InChI key
UEXCJVNBTNXOEH-UHFFFAOYSA-N
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一般描述
苯乙炔是一种芳香有机化合物，常用于Sonogashira偶联反应。苯乙炔在Rh和Pt复合物催化下形成聚苯乙炔。
应用
在存在三甲基铝的情况下，末端乙炔可用于将硝基转换到炔基羟基胺。
苯乙炔被用来研究钯催化苯乙炔氧化羰基化反应产物形成机制。
警示用语：
Danger
危险分类
Aquatic Chronic 3 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
80.6 °F - closed cup
闪点(°C)
27 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Rhodium and platinum complexes as catalysts for the polymerization of phenylacetylene.
Furlani A, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 24(5), 991-1005 (1986)
Tetrahedron Letters, 48, 1457-1457 (2007)
Katarina Novakovic et al.
Physical chemistry chemical physics : PCCP, 10(5), 749-753 (2008-02-07)
This paper reports on the influence of oscillations on product selectivity as well as the dynamics of product formation during the palladium-catalysed phenylacetylene oxidative carbonylation reaction in a catalytic system (PdI2, KI, Air, NaOAc in methanol). The occurrence of the
Shannon K Yee et al.
ACS nano, 5(11), 9256-9263 (2011-10-21)
The transport properties of a junction consisting of small donor-acceptor molecules bound to Au electrodes are studied and understood in terms of its hybrid donor-acceptor-electrode interfaces. A newly synthesized donor-acceptor molecule consisting of a bithiophene donor and a naphthalenediimide acceptor
Simon Rondeau-Gagné et al.
Journal of the American Chemical Society, 135(1), 110-113 (2012-12-20)
Soluble organic nanorods were prepared from phenylacetylene macrocycles using the topochemical polymerization of butadiyne moieties placed both inside and outside the macrocycles' skeletons. Macrocycles containing amide groups were self-assembled in a columnar fashion through the formation of an organogel in
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